Solubility in fluids close to their critical points

A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic c...

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Autor principal: Fern´ndez-Prim, R.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00334545_v67_n4_p519_FernndezPrim
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00334545_v67_n4_p519_FernndezPrim
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spelling todo:paper_00334545_v67_n4_p519_FernndezPrim2023-10-03T14:45:38Z Solubility in fluids close to their critical points Fern´ndez-Prim, R. A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic critical relations are a great help to evaluate data for volatile solutes, for solid solutes they help to separate contingent dependences of solubility from those which are essential. This analysis suggests there is no need to invoke the existence of critical clustering to explain the observed behaviour. © 1995 IUPAC JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00334545_v67_n4_p519_FernndezPrim
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description A feature of solubility in near-critical fluids is its strong dependence on pressure and temperature. A general thermodynamic procedure which describes the distribution of solutes between two coexisting phases, may be conveniently employed to describe solubility in near-critical fluids. Asymptotic critical relations are a great help to evaluate data for volatile solutes, for solid solutes they help to separate contingent dependences of solubility from those which are essential. This analysis suggests there is no need to invoke the existence of critical clustering to explain the observed behaviour. © 1995 IUPAC
format JOUR
author Fern´ndez-Prim, R.
spellingShingle Fern´ndez-Prim, R.
Solubility in fluids close to their critical points
author_facet Fern´ndez-Prim, R.
author_sort Fern´ndez-Prim, R.
title Solubility in fluids close to their critical points
title_short Solubility in fluids close to their critical points
title_full Solubility in fluids close to their critical points
title_fullStr Solubility in fluids close to their critical points
title_full_unstemmed Solubility in fluids close to their critical points
title_sort solubility in fluids close to their critical points
url http://hdl.handle.net/20.500.12110/paper_00334545_v67_n4_p519_FernndezPrim
work_keys_str_mv AT fernndezprimr solubilityinfluidsclosetotheircriticalpoints
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