Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol

Feeding experiments with [24-14C] 24-methylenecholesterol and mixtures of this sterol and [7-3H] 24-methylenecholesterol were performed to study the biosynthesis of withanolides in the plant Acnistus breviflorus. The results indicate that the side chain of the sterol precursor should be broken betwe...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Monteagudo, E.S., Burton, G., Gros, E.G.
Formato:	JOUR
Materias:	24-methylenecholesterol Acnistus breviflorus biosynthesis. jaborosalactone A jaborosalactone D Solanaceae withaferin A withanolides
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00319422_v35_n4_p927_Monteagudo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00319422_v35_n4_p927_Monteagudo
record_format	dspace
spelling	todo:paper_00319422_v35_n4_p927_Monteagudo2023-10-03T14:44:16Z Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol Monteagudo, E.S. Burton, G. Gros, E.G. 24-methylenecholesterol Acnistus breviflorus biosynthesis. jaborosalactone A jaborosalactone D Solanaceae withaferin A withanolides Feeding experiments with [24-14C] 24-methylenecholesterol and mixtures of this sterol and [7-3H] 24-methylenecholesterol were performed to study the biosynthesis of withanolides in the plant Acnistus breviflorus. The results indicate that the side chain of the sterol precursor should be broken between C-24 and C-25 to give an intermediate which follows the biogenetic pathway into withaferin A, jaborosalactone A and jaborosalactone D. © 1994. Fil:Monteagudo, E.S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00319422_v35_n4_p927_Monteagudo
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	24-methylenecholesterol Acnistus breviflorus biosynthesis. jaborosalactone A jaborosalactone D Solanaceae withaferin A withanolides
spellingShingle	24-methylenecholesterol Acnistus breviflorus biosynthesis. jaborosalactone A jaborosalactone D Solanaceae withaferin A withanolides Monteagudo, E.S. Burton, G. Gros, E.G. Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
topic_facet	24-methylenecholesterol Acnistus breviflorus biosynthesis. jaborosalactone A jaborosalactone D Solanaceae withaferin A withanolides
description	Feeding experiments with [24-14C] 24-methylenecholesterol and mixtures of this sterol and [7-3H] 24-methylenecholesterol were performed to study the biosynthesis of withanolides in the plant Acnistus breviflorus. The results indicate that the side chain of the sterol precursor should be broken between C-24 and C-25 to give an intermediate which follows the biogenetic pathway into withaferin A, jaborosalactone A and jaborosalactone D. © 1994.
format	JOUR
author	Monteagudo, E.S. Burton, G. Gros, E.G.
author_facet	Monteagudo, E.S. Burton, G. Gros, E.G.
author_sort	Monteagudo, E.S.
title	Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_short	Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_full	Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_fullStr	Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_full_unstemmed	Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_sort	biosynthesis of withanolides in acnistus breviflorus. incorporation of labelled 24-methylenecholesterol
url	http://hdl.handle.net/20.500.12110/paper_00319422_v35_n4_p927_Monteagudo
work_keys_str_mv	AT monteagudoes biosynthesisofwithanolidesinacnistusbreviflorusincorporationoflabelled24methylenecholesterol AT burtong biosynthesisofwithanolidesinacnistusbreviflorusincorporationoflabelled24methylenecholesterol AT groseg biosynthesisofwithanolidesinacnistusbreviflorusincorporationoflabelled24methylenecholesterol
_version_	1782025260070076416

Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol

Ejemplares similares