A pregnane glycoside from the roots of Mandevilla pentlandiana
A pregnane triglycoside containing a new genin 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one has been isolated from the dried roots of Mandevilla pentlandiana. Chemical and spectroscopic evidence for the glycoside are consistent with the structure 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O- β...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00319422_v32_n1_p171_Cabrera |
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todo:paper_00319422_v32_n1_p171_Cabrera2023-10-03T14:44:14Z A pregnane glycoside from the roots of Mandevilla pentlandiana Cabrera, G. Seldes, A.M. Gros, E.G. 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O-β-d-diginopyranosyl- (1→4)-O-β- d-cymaropyranosyl-(1→4) -O-β-d-cymaropyranoside. Apocynaceae glycoside Mandevilla pentlandiana glycoside pregnane derivative article carbohydrate analysis chemical structure chemistry isolation and purification molecular genetics nuclear magnetic resonance spectroscopy plant Carbohydrate Sequence Glycosides Magnetic Resonance Spectroscopy Molecular Sequence Data Molecular Structure Plants Pregnanes Support, Non-U.S. Gov't A pregnane triglycoside containing a new genin 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one has been isolated from the dried roots of Mandevilla pentlandiana. Chemical and spectroscopic evidence for the glycoside are consistent with the structure 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O- β-d-diginopyranosyl-(1→4)- O-β-d-cymaropyranosyl-(1→4)-O-β-d-cymaropyranoside. It is noteworthy that 3β,14β, 21-trihydroxy 5β-pregnan-20-one, biosynthetically related to the genin of this glycoside, has been proved to be a precursor of cardenolides, also produced by this plant. © 1993. Fil:Cabrera, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Seldes, A.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00319422_v32_n1_p171_Cabrera |
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Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O-β-d-diginopyranosyl- (1→4)-O-β- d-cymaropyranosyl-(1→4) -O-β-d-cymaropyranoside. Apocynaceae glycoside Mandevilla pentlandiana glycoside pregnane derivative article carbohydrate analysis chemical structure chemistry isolation and purification molecular genetics nuclear magnetic resonance spectroscopy plant Carbohydrate Sequence Glycosides Magnetic Resonance Spectroscopy Molecular Sequence Data Molecular Structure Plants Pregnanes Support, Non-U.S. Gov't |
| spellingShingle |
3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O-β-d-diginopyranosyl- (1→4)-O-β- d-cymaropyranosyl-(1→4) -O-β-d-cymaropyranoside. Apocynaceae glycoside Mandevilla pentlandiana glycoside pregnane derivative article carbohydrate analysis chemical structure chemistry isolation and purification molecular genetics nuclear magnetic resonance spectroscopy plant Carbohydrate Sequence Glycosides Magnetic Resonance Spectroscopy Molecular Sequence Data Molecular Structure Plants Pregnanes Support, Non-U.S. Gov't Cabrera, G. Seldes, A.M. Gros, E.G. A pregnane glycoside from the roots of Mandevilla pentlandiana |
| topic_facet |
3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O-β-d-diginopyranosyl- (1→4)-O-β- d-cymaropyranosyl-(1→4) -O-β-d-cymaropyranoside. Apocynaceae glycoside Mandevilla pentlandiana glycoside pregnane derivative article carbohydrate analysis chemical structure chemistry isolation and purification molecular genetics nuclear magnetic resonance spectroscopy plant Carbohydrate Sequence Glycosides Magnetic Resonance Spectroscopy Molecular Sequence Data Molecular Structure Plants Pregnanes Support, Non-U.S. Gov't |
| description |
A pregnane triglycoside containing a new genin 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one has been isolated from the dried roots of Mandevilla pentlandiana. Chemical and spectroscopic evidence for the glycoside are consistent with the structure 3β,14β-dihydroxy-21-methoxy-5β-pregnan-20-one-3-O- β-d-diginopyranosyl-(1→4)- O-β-d-cymaropyranosyl-(1→4)-O-β-d-cymaropyranoside. It is noteworthy that 3β,14β, 21-trihydroxy 5β-pregnan-20-one, biosynthetically related to the genin of this glycoside, has been proved to be a precursor of cardenolides, also produced by this plant. © 1993. |
| format |
JOUR |
| author |
Cabrera, G. Seldes, A.M. Gros, E.G. |
| author_facet |
Cabrera, G. Seldes, A.M. Gros, E.G. |
| author_sort |
Cabrera, G. |
| title |
A pregnane glycoside from the roots of Mandevilla pentlandiana |
| title_short |
A pregnane glycoside from the roots of Mandevilla pentlandiana |
| title_full |
A pregnane glycoside from the roots of Mandevilla pentlandiana |
| title_fullStr |
A pregnane glycoside from the roots of Mandevilla pentlandiana |
| title_full_unstemmed |
A pregnane glycoside from the roots of Mandevilla pentlandiana |
| title_sort |
pregnane glycoside from the roots of mandevilla pentlandiana |
| url |
http://hdl.handle.net/20.500.12110/paper_00319422_v32_n1_p171_Cabrera |
| work_keys_str_mv |
AT cabrerag apregnaneglycosidefromtherootsofmandevillapentlandiana AT seldesam apregnaneglycosidefromtherootsofmandevillapentlandiana AT groseg apregnaneglycosidefromtherootsofmandevillapentlandiana AT cabrerag pregnaneglycosidefromtherootsofmandevillapentlandiana AT seldesam pregnaneglycosidefromtherootsofmandevillapentlandiana AT groseg pregnaneglycosidefromtherootsofmandevillapentlandiana |
| _version_ |
1807319853272399872 |