Kinetic study of the thermal dehydration of copper(II) dipicolinates: Crystal and molecular structure of Cu(II) (pyridine 2,6-dicarboxylato) DI- and trihydrated

As a basis for the description of dehydration mechanisms, the molecular structures of two copper(II) dipicolinates, Cu(dipic).2H2O (triclinic) and Cu(dipic).3H2O, are presented and compared with those of other copper(II) dipicolinates. The kinetics of the isothermal dehydration of the monoclinic and...

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Detalles Bibliográficos
Autores principales: Sileo, E.E., Rigotti, G., Rivero, B.E., Blesa, M.A.
Formato: JOUR
Materias:
A. organometallic compounds
C. thermogravimetric analysis (TGA)
C. X-ray diffraction
D. crystal structure
Copper compounds
Crystal structure
Dehydration
Diffusion in solids
Mathematical models
Molecular structure
Optical microscopy
Reaction kinetics
Thermal effects
Thermogravimetric analysis
X ray crystallography
Avrami Erofe'ev model
Organometallics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00223697_v58_n7_p1127_Sileo
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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