The reaction of phenyllithium with carbon monoxide

Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediat...

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Autores principales: Nudelman, N.S., Vatale, A.A.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_0022328X_v241_n2_p143_Nudelman
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_0022328X_v241_n2_p143_Nudelman2023-10-03T14:31:33Z The reaction of phenyllithium with carbon monoxide Nudelman, N.S. Vatale, A.A. Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediates in the production of I, II and III. The basic sequences followed in the formation of those and of other minor products are outlined in the Scheme. Reaction conditions can be adjusted to obtain III in a high yield or to prevent further reaction of the first intermediate and obtain diarylalkylcarbinols, or substituted tetrahydrofurans. © 1983. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_0022328X_v241_n2_p143_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediates in the production of I, II and III. The basic sequences followed in the formation of those and of other minor products are outlined in the Scheme. Reaction conditions can be adjusted to obtain III in a high yield or to prevent further reaction of the first intermediate and obtain diarylalkylcarbinols, or substituted tetrahydrofurans. © 1983.
format JOUR
author Nudelman, N.S.
Vatale, A.A.
spellingShingle Nudelman, N.S.
Vatale, A.A.
The reaction of phenyllithium with carbon monoxide
author_facet Nudelman, N.S.
Vatale, A.A.
author_sort Nudelman, N.S.
title The reaction of phenyllithium with carbon monoxide
title_short The reaction of phenyllithium with carbon monoxide
title_full The reaction of phenyllithium with carbon monoxide
title_fullStr The reaction of phenyllithium with carbon monoxide
title_full_unstemmed The reaction of phenyllithium with carbon monoxide
title_sort reaction of phenyllithium with carbon monoxide
url http://hdl.handle.net/20.500.12110/paper_0022328X_v241_n2_p143_Nudelman
work_keys_str_mv AT nudelmanns thereactionofphenyllithiumwithcarbonmonoxide
AT vataleaa thereactionofphenyllithiumwithcarbonmonoxide
AT nudelmanns reactionofphenyllithiumwithcarbonmonoxide
AT vataleaa reactionofphenyllithiumwithcarbonmonoxide
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