The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose

The reaction of methanolic ammonia with α-octa-O-acetylcellobiose is described. From the reaction were isolated cellobiose, N,N′-diacetylcellobiosylidenediamine, and a hepta-O-acetyl-N-acetylcellobiosylamine which is considered the alpha anomer of the product already described as hepta-O-acetyl-N-ac...

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Autores principales: Deferrari, J.O., Cadenas, R.A.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00223263_v28_n4_p1070_Deferrari
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00223263_v28_n4_p1070_Deferrari2023-10-03T14:31:11Z The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose Deferrari, J.O. Cadenas, R.A. The reaction of methanolic ammonia with α-octa-O-acetylcellobiose is described. From the reaction were isolated cellobiose, N,N′-diacetylcellobiosylidenediamine, and a hepta-O-acetyl-N-acetylcellobiosylamine which is considered the alpha anomer of the product already described as hepta-O-acetyl-N-acetylcellobiosylamine. The acetyl derivative of N,N′-diacetylcellobiosylidenediamine was prepared and the influence of solvent upon the reaction studied is discussed. © 1963, American Chemical Society. All rights reserved. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cadenas, R.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00223263_v28_n4_p1070_Deferrari
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The reaction of methanolic ammonia with α-octa-O-acetylcellobiose is described. From the reaction were isolated cellobiose, N,N′-diacetylcellobiosylidenediamine, and a hepta-O-acetyl-N-acetylcellobiosylamine which is considered the alpha anomer of the product already described as hepta-O-acetyl-N-acetylcellobiosylamine. The acetyl derivative of N,N′-diacetylcellobiosylidenediamine was prepared and the influence of solvent upon the reaction studied is discussed. © 1963, American Chemical Society. All rights reserved.
format JOUR
author Deferrari, J.O.
Cadenas, R.A.
spellingShingle Deferrari, J.O.
Cadenas, R.A.
The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose
author_facet Deferrari, J.O.
Cadenas, R.A.
author_sort Deferrari, J.O.
title The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose
title_short The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose
title_full The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose
title_fullStr The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose
title_full_unstemmed The Reaction of Ammonia with Acylated Disaccharides. I. Acetyl Derivatives of Cellobiose
title_sort reaction of ammonia with acylated disaccharides. i. acetyl derivatives of cellobiose
url http://hdl.handle.net/20.500.12110/paper_00223263_v28_n4_p1070_Deferrari
work_keys_str_mv AT deferrarijo thereactionofammoniawithacylateddisaccharidesiacetylderivativesofcellobiose
AT cadenasra thereactionofammoniawithacylateddisaccharidesiacetylderivativesofcellobiose
AT deferrarijo reactionofammoniawithacylateddisaccharidesiacetylderivativesofcellobiose
AT cadenasra reactionofammoniawithacylateddisaccharidesiacetylderivativesofcellobiose
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