The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar t...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu |
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todo:paper_00223263_v17_n8_p1087_Deulofeu2023-10-03T14:31:09Z The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation Deulofeu, V. Deferrari, J.O. 1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved. Fil:Deulofeu, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved. |
| format |
JOUR |
| author |
Deulofeu, V. Deferrari, J.O. |
| spellingShingle |
Deulofeu, V. Deferrari, J.O. The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
| author_facet |
Deulofeu, V. Deferrari, J.O. |
| author_sort |
Deulofeu, V. |
| title |
The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
| title_short |
The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
| title_full |
The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
| title_fullStr |
The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
| title_full_unstemmed |
The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation |
| title_sort |
reaction of ammonia with some acetylated and benzoylated monosaccharides. i. d-glucose derivatives and an interpretation |
| url |
http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu |
| work_keys_str_mv |
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| _version_ |
1807317332304855040 |