Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II

The syntheses of 2,3-dihydro-1,3,4-thiadiazoles and 1,3,4-thiadiazoles from 1,2-O-isopropylidene-α-D-xylo-1,5-pentadialdo-1,4-furanose thiosemicarbazone are described. The new compounds as well as the intermediate products are physically and spectroscopically characterized. We discuss a possible mec...

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Detalles Bibliográficos
Autores principales:	Martins Alho, M.A., D'Accorso, N.B.
Formato:	JOUR
Materias:	thiosemicarbazone derivative acetylation acylation article cyclization proton nuclear magnetic resonance reaction analysis synthesis thermodynamics
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_0022152X_v37_n4_p811_MartinsAlho
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_0022152X_v37_n4_p811_MartinsAlho
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spelling	todo:paper_0022152X_v37_n4_p811_MartinsAlho2023-10-03T14:27:45Z Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II Martins Alho, M.A. D'Accorso, N.B. thiosemicarbazone derivative acetylation acylation article cyclization proton nuclear magnetic resonance reaction analysis synthesis thermodynamics The syntheses of 2,3-dihydro-1,3,4-thiadiazoles and 1,3,4-thiadiazoles from 1,2-O-isopropylidene-α-D-xylo-1,5-pentadialdo-1,4-furanose thiosemicarbazone are described. The new compounds as well as the intermediate products are physically and spectroscopically characterized. We discuss a possible mechanistic pathway for heterocyclization in this particular substrate, using computational calculation. Fil:Martins Alho, M.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:D'Accorso, N.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_0022152X_v37_n4_p811_MartinsAlho
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	thiosemicarbazone derivative acetylation acylation article cyclization proton nuclear magnetic resonance reaction analysis synthesis thermodynamics
spellingShingle	thiosemicarbazone derivative acetylation acylation article cyclization proton nuclear magnetic resonance reaction analysis synthesis thermodynamics Martins Alho, M.A. D'Accorso, N.B. Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II
topic_facet	thiosemicarbazone derivative acetylation acylation article cyclization proton nuclear magnetic resonance reaction analysis synthesis thermodynamics
description	The syntheses of 2,3-dihydro-1,3,4-thiadiazoles and 1,3,4-thiadiazoles from 1,2-O-isopropylidene-α-D-xylo-1,5-pentadialdo-1,4-furanose thiosemicarbazone are described. The new compounds as well as the intermediate products are physically and spectroscopically characterized. We discuss a possible mechanistic pathway for heterocyclization in this particular substrate, using computational calculation.
format	JOUR
author	Martins Alho, M.A. D'Accorso, N.B.
author_facet	Martins Alho, M.A. D'Accorso, N.B.
author_sort	Martins Alho, M.A.
title	Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II
title_short	Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II
title_full	Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II
title_fullStr	Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II
title_full_unstemmed	Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II
title_sort	synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - part ii
url	http://hdl.handle.net/20.500.12110/paper_0022152X_v37_n4_p811_MartinsAlho
work_keys_str_mv	AT martinsalhoma synthesisandcharacterizationofsomeheterocyclicderivativesbycyclizationofcarbohydratethiosemicarbazonepartii AT daccorsonb synthesisandcharacterizationofsomeheterocyclicderivativesbycyclizationofcarbohydratethiosemicarbazonepartii
_version_	1807314526317576192

Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part II

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