On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles

Chloro derivatives of N-methylcarbazole (1), N-phenylcarbazole (2), N-acetylcarbazole (3), N-benzoylcarbazole (4) and 2-methoxy-N-methylcarbazole are synthesized. They are compounds 1a, 1b, 1e, 1d, 1e, 2a, 2b, 3a, 3b, 3c, 3d, 4a, 4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first ti...

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Autores principales: Bonesi, S.M., Erra-Balsells, R.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_0022152X_v34_n3_p891_Bonesi
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_0022152X_v34_n3_p891_Bonesi2023-10-03T14:27:42Z On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles Bonesi, S.M. Erra-Balsells, R. Chloro derivatives of N-methylcarbazole (1), N-phenylcarbazole (2), N-acetylcarbazole (3), N-benzoylcarbazole (4) and 2-methoxy-N-methylcarbazole are synthesized. They are compounds 1a, 1b, 1e, 1d, 1e, 2a, 2b, 3a, 3b, 3c, 3d, 4a, 4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first time. By using semiempirical PM3 method theoretical substituent effects on the chlorinating reaction are calculated. A chlorination mechanism of carbazoles and N-substituted carbazoles are compared. Fil:Bonesi, S.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_0022152X_v34_n3_p891_Bonesi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Chloro derivatives of N-methylcarbazole (1), N-phenylcarbazole (2), N-acetylcarbazole (3), N-benzoylcarbazole (4) and 2-methoxy-N-methylcarbazole are synthesized. They are compounds 1a, 1b, 1e, 1d, 1e, 2a, 2b, 3a, 3b, 3c, 3d, 4a, 4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first time. By using semiempirical PM3 method theoretical substituent effects on the chlorinating reaction are calculated. A chlorination mechanism of carbazoles and N-substituted carbazoles are compared.
format JOUR
author Bonesi, S.M.
Erra-Balsells, R.
spellingShingle Bonesi, S.M.
Erra-Balsells, R.
On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
author_facet Bonesi, S.M.
Erra-Balsells, R.
author_sort Bonesi, S.M.
title On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_short On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_full On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_fullStr On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_full_unstemmed On the Synthesis and Isolation of Chlorocarbazoles Obtained by Chlorination of N-Substituted Carbazoles
title_sort on the synthesis and isolation of chlorocarbazoles obtained by chlorination of n-substituted carbazoles
url http://hdl.handle.net/20.500.12110/paper_0022152X_v34_n3_p891_Bonesi
work_keys_str_mv AT bonesism onthesynthesisandisolationofchlorocarbazolesobtainedbychlorinationofnsubstitutedcarbazoles
AT errabalsellsr onthesynthesisandisolationofchlorocarbazolesobtainedbychlorinationofnsubstitutedcarbazoles
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