Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD
Delamination and restacking of dodecyl-sulfate-intercalated hydrotalcite in CCl4 and toluene were followed by in situ low-angle XRD. It is shown that exfoliation of hybrid layered double hydroxides must be rationalized in terms of the miscibility of the solvent and the aliphatic chains of the interc...
Guardado en:
| Autores principales: | , |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00219797_v275_n1_p345_Jobbagy |
| Aporte de: |
| id |
todo:paper_00219797_v275_n1_p345_Jobbagy |
|---|---|
| record_format |
dspace |
| spelling |
todo:paper_00219797_v275_n1_p345_Jobbagy2023-10-03T14:25:11Z Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD Jobbágy, M. Regazzoni, A.E. Delamination In situ processing Solubility Solvents X ray diffraction Double hydroxides Exfoliation Hydrotalcites Restacking Carbon tetrachloride aliphatic compound amphophile anion chloride dodecyl sulfate hydrotalcite hydroxide solvent toluene article dilution hybrid intercalation complex miscibility priority journal X ray diffraction Delamination and restacking of dodecyl-sulfate-intercalated hydrotalcite in CCl4 and toluene were followed by in situ low-angle XRD. It is shown that exfoliation of hybrid layered double hydroxides must be rationalized in terms of the miscibility of the solvent and the aliphatic chains of the intercalated amphiphilic anions. The macroscopic appearance of diluted systems, however, is determined by the interaction between the edges of the exfoliated lamella. © 2004 Elsevier Inc. All rights reserved. Fil:Jobbágy, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00219797_v275_n1_p345_Jobbagy |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Delamination In situ processing Solubility Solvents X ray diffraction Double hydroxides Exfoliation Hydrotalcites Restacking Carbon tetrachloride aliphatic compound amphophile anion chloride dodecyl sulfate hydrotalcite hydroxide solvent toluene article dilution hybrid intercalation complex miscibility priority journal X ray diffraction |
| spellingShingle |
Delamination In situ processing Solubility Solvents X ray diffraction Double hydroxides Exfoliation Hydrotalcites Restacking Carbon tetrachloride aliphatic compound amphophile anion chloride dodecyl sulfate hydrotalcite hydroxide solvent toluene article dilution hybrid intercalation complex miscibility priority journal X ray diffraction Jobbágy, M. Regazzoni, A.E. Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
| topic_facet |
Delamination In situ processing Solubility Solvents X ray diffraction Double hydroxides Exfoliation Hydrotalcites Restacking Carbon tetrachloride aliphatic compound amphophile anion chloride dodecyl sulfate hydrotalcite hydroxide solvent toluene article dilution hybrid intercalation complex miscibility priority journal X ray diffraction |
| description |
Delamination and restacking of dodecyl-sulfate-intercalated hydrotalcite in CCl4 and toluene were followed by in situ low-angle XRD. It is shown that exfoliation of hybrid layered double hydroxides must be rationalized in terms of the miscibility of the solvent and the aliphatic chains of the intercalated amphiphilic anions. The macroscopic appearance of diluted systems, however, is determined by the interaction between the edges of the exfoliated lamella. © 2004 Elsevier Inc. All rights reserved. |
| format |
JOUR |
| author |
Jobbágy, M. Regazzoni, A.E. |
| author_facet |
Jobbágy, M. Regazzoni, A.E. |
| author_sort |
Jobbágy, M. |
| title |
Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
| title_short |
Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
| title_full |
Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
| title_fullStr |
Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
| title_full_unstemmed |
Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD |
| title_sort |
delamination and restacking of hybrid layered double hydroxides assessed by in situ xrd |
| url |
http://hdl.handle.net/20.500.12110/paper_00219797_v275_n1_p345_Jobbagy |
| work_keys_str_mv |
AT jobbagym delaminationandrestackingofhybridlayereddoublehydroxidesassessedbyinsituxrd AT regazzoniae delaminationandrestackingofhybridlayereddoublehydroxidesassessedbyinsituxrd |
| _version_ |
1807319641734774784 |