Paper electrophoresis of sugars with cetyltrimethylammonium borate

Paper electrophoresis of sugars and other substances with cetyltrimethylammonium borate at pH 9.6 gives rise to a pattern of mobilities different from that found with potassium borate, thus making certain separations possible that are not obtained with the potassium salt. There seems to be a general...

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Autores principales: Piras, R., Cabib, E.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00219673_v8_nC_p63_Piras
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spelling todo:paper_00219673_v8_nC_p63_Piras2023-10-03T14:25:02Z Paper electrophoresis of sugars with cetyltrimethylammonium borate Piras, R. Cabib, E. boric acid carbohydrate article BORATES/chemistry CARBOHYDRATES/chemistry chemistry electrophoresis BORATES/chemistry CARBOHYDRATES/chemistry ELECTROPHORESIS Borates Carbohydrates Electrophoresis Paper electrophoresis of sugars and other substances with cetyltrimethylammonium borate at pH 9.6 gives rise to a pattern of mobilities different from that found with potassium borate, thus making certain separations possible that are not obtained with the potassium salt. There seems to be a general trend towards a reversal in the order of mobilities with the cetyltrimethylammonium buffer. The observed mobilities have been interpreted as the net results of two contrary effects: a strong and uniform endosmotic flow towards the anode and an opposite and variable movement towards the cathode. The latter displacement would take place by association of the solutes with the positively charged ionic micelles that are present in the solutions of cetyltrimethylammonium salts. Applications of this behavior might lead to the separation of other substances. © 1962. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00219673_v8_nC_p63_Piras
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic boric acid
carbohydrate
article
BORATES/chemistry
CARBOHYDRATES/chemistry
chemistry
electrophoresis
BORATES/chemistry
CARBOHYDRATES/chemistry
ELECTROPHORESIS
Borates
Carbohydrates
Electrophoresis
spellingShingle boric acid
carbohydrate
article
BORATES/chemistry
CARBOHYDRATES/chemistry
chemistry
electrophoresis
BORATES/chemistry
CARBOHYDRATES/chemistry
ELECTROPHORESIS
Borates
Carbohydrates
Electrophoresis
Piras, R.
Cabib, E.
Paper electrophoresis of sugars with cetyltrimethylammonium borate
topic_facet boric acid
carbohydrate
article
BORATES/chemistry
CARBOHYDRATES/chemistry
chemistry
electrophoresis
BORATES/chemistry
CARBOHYDRATES/chemistry
ELECTROPHORESIS
Borates
Carbohydrates
Electrophoresis
description Paper electrophoresis of sugars and other substances with cetyltrimethylammonium borate at pH 9.6 gives rise to a pattern of mobilities different from that found with potassium borate, thus making certain separations possible that are not obtained with the potassium salt. There seems to be a general trend towards a reversal in the order of mobilities with the cetyltrimethylammonium buffer. The observed mobilities have been interpreted as the net results of two contrary effects: a strong and uniform endosmotic flow towards the anode and an opposite and variable movement towards the cathode. The latter displacement would take place by association of the solutes with the positively charged ionic micelles that are present in the solutions of cetyltrimethylammonium salts. Applications of this behavior might lead to the separation of other substances. © 1962.
format JOUR
author Piras, R.
Cabib, E.
author_facet Piras, R.
Cabib, E.
author_sort Piras, R.
title Paper electrophoresis of sugars with cetyltrimethylammonium borate
title_short Paper electrophoresis of sugars with cetyltrimethylammonium borate
title_full Paper electrophoresis of sugars with cetyltrimethylammonium borate
title_fullStr Paper electrophoresis of sugars with cetyltrimethylammonium borate
title_full_unstemmed Paper electrophoresis of sugars with cetyltrimethylammonium borate
title_sort paper electrophoresis of sugars with cetyltrimethylammonium borate
url http://hdl.handle.net/20.500.12110/paper_00219673_v8_nC_p63_Piras
work_keys_str_mv AT pirasr paperelectrophoresisofsugarswithcetyltrimethylammoniumborate
AT cabibe paperelectrophoresisofsugarswithcetyltrimethylammoniumborate
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