Solubility of two stable iminium salts in 12 polar solvents

Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function...

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Detalles Bibliográficos
Autores principales:	Grande, M.C., Barrero, C.R., Marschoff, C.M., Rodríguez, J.B., Gros, E.G.
Formato:	JOUR
Materias:	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00219568_v47_n6_p1337_Grande
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_00219568_v47_n6_p1337_Grande
record_format	dspace
spelling	todo:paper_00219568_v47_n6_p1337_Grande2023-10-03T14:23:39Z Solubility of two stable iminium salts in 12 polar solvents Grande, M.C. Barrero, C.R. Marschoff, C.M. Rodríguez, J.B. Gros, E.G. Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated. Fil:Marschoff, C.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Rodríguez, J.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00219568_v47_n6_p1337_Grande
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds
spellingShingle	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds Grande, M.C. Barrero, C.R. Marschoff, C.M. Rodríguez, J.B. Gros, E.G. Solubility of two stable iminium salts in 12 polar solvents
topic_facet	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds
description	Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
format	JOUR
author	Grande, M.C. Barrero, C.R. Marschoff, C.M. Rodríguez, J.B. Gros, E.G.
author_facet	Grande, M.C. Barrero, C.R. Marschoff, C.M. Rodríguez, J.B. Gros, E.G.
author_sort	Grande, M.C.
title	Solubility of two stable iminium salts in 12 polar solvents
title_short	Solubility of two stable iminium salts in 12 polar solvents
title_full	Solubility of two stable iminium salts in 12 polar solvents
title_fullStr	Solubility of two stable iminium salts in 12 polar solvents
title_full_unstemmed	Solubility of two stable iminium salts in 12 polar solvents
title_sort	solubility of two stable iminium salts in 12 polar solvents
url	http://hdl.handle.net/20.500.12110/paper_00219568_v47_n6_p1337_Grande
work_keys_str_mv	AT grandemc solubilityoftwostableiminiumsaltsin12polarsolvents AT barrerocr solubilityoftwostableiminiumsaltsin12polarsolvents AT marschoffcm solubilityoftwostableiminiumsaltsin12polarsolvents AT rodriguezjb solubilityoftwostableiminiumsaltsin12polarsolvents AT groseg solubilityoftwostableiminiumsaltsin12polarsolvents
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Solubility of two stable iminium salts in 12 polar solvents

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