Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system
The synthesis and structural characterization of four new copper compounds with formula [Cu(crot)2(isn)2(Hcrot)·H 2O] (1), [Cu(oda)(isn)2] (2), [Cu(crot) 2(nia)2·(H2O)] (3) and [Cu(oda)(nia)] (4) (crot = trans-2-butenoate, oda = oxydiacetate, isn = isonicotinamide, nia = nicotinamide) is reported. T...
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todo:paper_00201693_v373_n1_p117_Perec2023-10-03T14:17:21Z Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system Perec, M. Baggio, R.F. Peña, O. Sartoris, R.P. Calvo, R. Copper compound EPR H-bonded assembly Isonicotinamide Nicotinamide The synthesis and structural characterization of four new copper compounds with formula [Cu(crot)2(isn)2(Hcrot)·H 2O] (1), [Cu(oda)(isn)2] (2), [Cu(crot) 2(nia)2·(H2O)] (3) and [Cu(oda)(nia)] (4) (crot = trans-2-butenoate, oda = oxydiacetate, isn = isonicotinamide, nia = nicotinamide) is reported. The complexes extend into 3D supramolecular structures by means of hydrogen bonds. EPR spectra of powder samples of the compounds are reported. © 2011 Elsevier B.V. All rights reserved. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v373_n1_p117_Perec |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Copper compound EPR H-bonded assembly Isonicotinamide Nicotinamide |
spellingShingle |
Copper compound EPR H-bonded assembly Isonicotinamide Nicotinamide Perec, M. Baggio, R.F. Peña, O. Sartoris, R.P. Calvo, R. Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system |
topic_facet |
Copper compound EPR H-bonded assembly Isonicotinamide Nicotinamide |
description |
The synthesis and structural characterization of four new copper compounds with formula [Cu(crot)2(isn)2(Hcrot)·H 2O] (1), [Cu(oda)(isn)2] (2), [Cu(crot) 2(nia)2·(H2O)] (3) and [Cu(oda)(nia)] (4) (crot = trans-2-butenoate, oda = oxydiacetate, isn = isonicotinamide, nia = nicotinamide) is reported. The complexes extend into 3D supramolecular structures by means of hydrogen bonds. EPR spectra of powder samples of the compounds are reported. © 2011 Elsevier B.V. All rights reserved. |
format |
JOUR |
author |
Perec, M. Baggio, R.F. Peña, O. Sartoris, R.P. Calvo, R. |
author_facet |
Perec, M. Baggio, R.F. Peña, O. Sartoris, R.P. Calvo, R. |
author_sort |
Perec, M. |
title |
Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system |
title_short |
Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system |
title_full |
Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system |
title_fullStr |
Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system |
title_full_unstemmed |
Synthesis and structures of four new compounds of the copper(II)- carboxylate-pyridinecarboxamide system |
title_sort |
synthesis and structures of four new compounds of the copper(ii)- carboxylate-pyridinecarboxamide system |
url |
http://hdl.handle.net/20.500.12110/paper_00201693_v373_n1_p117_Perec |
work_keys_str_mv |
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1807321785248514048 |