A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties
A seven-coordinate FeIII complex, [Fe(oda)(H2O)2(NO3)], was obtained after dissolving Fe(NO3)3 · 9H2O in an aqueous solution of oxydiacetic acid (H2oda) at room temperature. In the solid state, the FeIII center adopts a pentagonal bipyramid geometry with an {FeO7} core formed by a tridentate oda2- a...
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todo:paper_00201693_v360_n9_p2911_Slep2023-10-03T14:17:20Z A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties Slep, L.D. Calvo, R. Nascimento, O.R. Baggio, R. Garland, M.T. Peña, O. Perec, M. EPR FeIII Magnetic properties Oxydiacetato X-ray crystal structure A seven-coordinate FeIII complex, [Fe(oda)(H2O)2(NO3)], was obtained after dissolving Fe(NO3)3 · 9H2O in an aqueous solution of oxydiacetic acid (H2oda) at room temperature. In the solid state, the FeIII center adopts a pentagonal bipyramid geometry with an {FeO7} core formed by a tridentate oda2- and a bidentate NO3- in the equatorial plane, and two axial water molecules. Magnetic measurements and EPR spectra revealed the presence of S = 5/2 FeIII centers with rhombic zero field splitting parameters (D = 0.81 cm-1, E/D = 0.33 ). Weak antiferromagnetic interactions with J ≈ -0.06 cm-1 operating between neighboring Fe ions connected through Fe-O-C-O⋯H-O-Fe paths are estimated using the molecular field approximation. © 2007 Elsevier B.V. All rights reserved. Fil:Slep, L.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v360_n9_p2911_Slep |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
EPR FeIII Magnetic properties Oxydiacetato X-ray crystal structure |
| spellingShingle |
EPR FeIII Magnetic properties Oxydiacetato X-ray crystal structure Slep, L.D. Calvo, R. Nascimento, O.R. Baggio, R. Garland, M.T. Peña, O. Perec, M. A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties |
| topic_facet |
EPR FeIII Magnetic properties Oxydiacetato X-ray crystal structure |
| description |
A seven-coordinate FeIII complex, [Fe(oda)(H2O)2(NO3)], was obtained after dissolving Fe(NO3)3 · 9H2O in an aqueous solution of oxydiacetic acid (H2oda) at room temperature. In the solid state, the FeIII center adopts a pentagonal bipyramid geometry with an {FeO7} core formed by a tridentate oda2- and a bidentate NO3- in the equatorial plane, and two axial water molecules. Magnetic measurements and EPR spectra revealed the presence of S = 5/2 FeIII centers with rhombic zero field splitting parameters (D = 0.81 cm-1, E/D = 0.33 ). Weak antiferromagnetic interactions with J ≈ -0.06 cm-1 operating between neighboring Fe ions connected through Fe-O-C-O⋯H-O-Fe paths are estimated using the molecular field approximation. © 2007 Elsevier B.V. All rights reserved. |
| format |
JOUR |
| author |
Slep, L.D. Calvo, R. Nascimento, O.R. Baggio, R. Garland, M.T. Peña, O. Perec, M. |
| author_facet |
Slep, L.D. Calvo, R. Nascimento, O.R. Baggio, R. Garland, M.T. Peña, O. Perec, M. |
| author_sort |
Slep, L.D. |
| title |
A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties |
| title_short |
A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties |
| title_full |
A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties |
| title_fullStr |
A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties |
| title_full_unstemmed |
A seven-coordinate FeIII compound: [Fe{O(CH2CO2)2}(H2O) 2(NO3)]. Preparation, structure and magnetic properties |
| title_sort |
seven-coordinate feiii compound: [fe{o(ch2co2)2}(h2o) 2(no3)]. preparation, structure and magnetic properties |
| url |
http://hdl.handle.net/20.500.12110/paper_00201693_v360_n9_p2911_Slep |
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