New homobinuclear carboxylate-bridged gadolinium(III) complexes
Two novel gadolinium(III) trans-2-butenoate dimeric compounds [Gd 2(O2CCH=CHCH3)6(H2O) 4]·2H2O (1) and [Gd2(O 2CCH=CHCH3)6(phen)2]·2H 2O (2) have been synthesized via hydrothermal routes. Compound 1 consists of two independent dimers in the unit cell, one is doubly bridged (η2:η1:μ2) and the other q...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201693_v353_n_p315_Rizzi |
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todo:paper_00201693_v353_n_p315_Rizzi2023-10-03T14:17:18Z New homobinuclear carboxylate-bridged gadolinium(III) complexes Rizzi, A. Baggio, R. Garland, M.T. Peña, O. Perec, M. Carboxylate complexes Gadolinium dimers Magnetism Structural chemistry bridged compound carboxylic acid derivative dimer gadolinium article crystal structure magnetism molecular interaction synthesis trans isomer X ray crystallography Two novel gadolinium(III) trans-2-butenoate dimeric compounds [Gd 2(O2CCH=CHCH3)6(H2O) 4]·2H2O (1) and [Gd2(O 2CCH=CHCH3)6(phen)2]·2H 2O (2) have been synthesized via hydrothermal routes. Compound 1 consists of two independent dimers in the unit cell, one is doubly bridged (η2:η1:μ2) and the other quadruply bridged (two η1:η1:μ2 and two η2:η1:μ2). Compound 2 is dimeric with a quadruply bridged core (two η1:η1:μ 2 and two η2:η1:μ2). Magnetic measurements for 2 show that there is a weak antiferromagnetic intramolecular Gd⋯Gd interaction. © 2003 Elsevier B.V. All rights reserved. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v353_n_p315_Rizzi |
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Universidad de Buenos Aires |
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I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Carboxylate complexes Gadolinium dimers Magnetism Structural chemistry bridged compound carboxylic acid derivative dimer gadolinium article crystal structure magnetism molecular interaction synthesis trans isomer X ray crystallography |
| spellingShingle |
Carboxylate complexes Gadolinium dimers Magnetism Structural chemistry bridged compound carboxylic acid derivative dimer gadolinium article crystal structure magnetism molecular interaction synthesis trans isomer X ray crystallography Rizzi, A. Baggio, R. Garland, M.T. Peña, O. Perec, M. New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| topic_facet |
Carboxylate complexes Gadolinium dimers Magnetism Structural chemistry bridged compound carboxylic acid derivative dimer gadolinium article crystal structure magnetism molecular interaction synthesis trans isomer X ray crystallography |
| description |
Two novel gadolinium(III) trans-2-butenoate dimeric compounds [Gd 2(O2CCH=CHCH3)6(H2O) 4]·2H2O (1) and [Gd2(O 2CCH=CHCH3)6(phen)2]·2H 2O (2) have been synthesized via hydrothermal routes. Compound 1 consists of two independent dimers in the unit cell, one is doubly bridged (η2:η1:μ2) and the other quadruply bridged (two η1:η1:μ2 and two η2:η1:μ2). Compound 2 is dimeric with a quadruply bridged core (two η1:η1:μ 2 and two η2:η1:μ2). Magnetic measurements for 2 show that there is a weak antiferromagnetic intramolecular Gd⋯Gd interaction. © 2003 Elsevier B.V. All rights reserved. |
| format |
JOUR |
| author |
Rizzi, A. Baggio, R. Garland, M.T. Peña, O. Perec, M. |
| author_facet |
Rizzi, A. Baggio, R. Garland, M.T. Peña, O. Perec, M. |
| author_sort |
Rizzi, A. |
| title |
New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| title_short |
New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| title_full |
New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| title_fullStr |
New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| title_full_unstemmed |
New homobinuclear carboxylate-bridged gadolinium(III) complexes |
| title_sort |
new homobinuclear carboxylate-bridged gadolinium(iii) complexes |
| url |
http://hdl.handle.net/20.500.12110/paper_00201693_v353_n_p315_Rizzi |
| work_keys_str_mv |
AT rizzia newhomobinuclearcarboxylatebridgedgadoliniumiiicomplexes AT baggior newhomobinuclearcarboxylatebridgedgadoliniumiiicomplexes AT garlandmt newhomobinuclearcarboxylatebridgedgadoliniumiiicomplexes AT penao newhomobinuclearcarboxylatebridgedgadoliniumiiicomplexes AT perecm newhomobinuclearcarboxylatebridgedgadoliniumiiicomplexes |
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1807319153170710528 |