The valence-localized decacyanodiruthenium(III,II) analogue of the Creutz-Taube ion. Completing the full d5/d6 triad [(NC)5M(μ-pz)M(CN)5]5-, M = Fe,Ru,Os; pz = pyrazine

The new ruthenium(II) complex ion [(NC)5Ru(μ-pz)Ru(CN)5]6- has been prepared and studied as the hexakis(tetraethylammonium) salt. Although spectroelectrochemical experiments in dichloromethane were affected by adsorption as they were in other solvents, the compound could be oxidized via two reversib...

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Detalles Bibliográficos
Autores principales:	Scheiring, T., Kaim, W., Olabe, J.A., Parise, A.R., Fiedler, J.
Formato:	JOUR
Materias:	Cyano complexes Mixed-valence complexes Ruthenium complexes Spectroelectrochemistry pyrazine derivative ruthenium derivative article complex formation Czech Republic electrochemistry Germany molecular interaction oxidation reduction reaction
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201693_v300-302_n_p125_Scheiring
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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