A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)

The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper wea...

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Autores principales: Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., Vega, A.
Formato: JOUR
Materias:
Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00201693_v286_n1_p74_Baggio
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00201693_v286_n1_p74_Baggio2023-10-03T14:17:15Z A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline) Baggio, R. Garland, M.T. Manzur, J. Peña, O. Perec, M. Spodine, E. Vega, A. Carboxylate complexes Copper complexes Crystal structures Dinuclear complexes Thioether complexes The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge. © 1999 Elsevier Science S.A. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v286_n1_p74_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
spellingShingle Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
Baggio, R.
Garland, M.T.
Manzur, J.
Peña, O.
Perec, M.
Spodine, E.
Vega, A.
A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
topic_facet Carboxylate complexes
Copper complexes
Crystal structures
Dinuclear complexes
Thioether complexes
description The dinuclear copper(II) complex [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate; phen=1,10-phenanthroline) has been prepared and characterized by single crystal X-ray diffraction. The dimer shows a strictly planar CuO2Cu ring involving monoatomic O-carboxylates in the bridging mode with each copper weakly bonded to a thioether in a distorted octahedral N2O3S environment. Variable temperature susceptibility measurements reveal the existence of weak ferromagnetic interactions within the dimer, mediated by the oxygen atoms of the bridge. © 1999 Elsevier Science S.A.
format JOUR
author Baggio, R.
Garland, M.T.
Manzur, J.
Peña, O.
Perec, M.
Spodine, E.
Vega, A.
author_facet Baggio, R.
Garland, M.T.
Manzur, J.
Peña, O.
Perec, M.
Spodine, E.
Vega, A.
author_sort Baggio, R.
title A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_short A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_full A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_fullStr A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_full_unstemmed A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
title_sort dinuclear copper(ii) complex involving monoatomic o-carboxylate bridging and cu-s(thioether) bonds: [cu(tda)(phen)]2 · h2tda (tda=thiodiacetate, phen=phenanthroline)
url http://hdl.handle.net/20.500.12110/paper_00201693_v286_n1_p74_Baggio
work_keys_str_mv AT baggior adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT garlandmt adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT manzurj adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT penao adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT perecm adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT spodinee adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT vegaa adinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT baggior dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT garlandmt dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT manzurj dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT penao dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT perecm dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT spodinee dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
AT vegaa dinuclearcopperiicomplexinvolvingmonoatomicocarboxylatebridgingandcusthioetherbondscutdaphen2h2tdatdathiodiacetatephenphenanthroline
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