Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes
In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)RuII(L)4(μ-CN)RuII(py) 4Cl]PF6 and trans-[RuII(L)4{(μ- CN)RuII(py)4Cl}2](PF6)2 (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v52_n6_p2906_Pieslinger |
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todo:paper_00201669_v52_n6_p2906_Pieslinger2023-10-03T14:17:07Z Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes Pieslinger, G.E. Albores, P. Slep, L.D. Coe, B.J. Timpson, C.J. Baraldo, L.M. In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)RuII(L)4(μ-CN)RuII(py) 4Cl]PF6 and trans-[RuII(L)4{(μ- CN)RuII(py)4Cl}2](PF6)2 (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show a variety of metal-to-metal charge-transfer bands, including one arising from charge transfer between the remote ruthenium units. The latter is more intense when L = 4-methoxypyridine and points to the role of the bridging ruthenium unit in promoting mixing between the dπ orbitals of the terminal fragments. © 2013 American Chemical Society. Fil:Albores, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Slep, L.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baraldo, L.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201669_v52_n6_p2906_Pieslinger |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)RuII(L)4(μ-CN)RuII(py) 4Cl]PF6 and trans-[RuII(L)4{(μ- CN)RuII(py)4Cl}2](PF6)2 (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show a variety of metal-to-metal charge-transfer bands, including one arising from charge transfer between the remote ruthenium units. The latter is more intense when L = 4-methoxypyridine and points to the role of the bridging ruthenium unit in promoting mixing between the dπ orbitals of the terminal fragments. © 2013 American Chemical Society. |
| format |
JOUR |
| author |
Pieslinger, G.E. Albores, P. Slep, L.D. Coe, B.J. Timpson, C.J. Baraldo, L.M. |
| spellingShingle |
Pieslinger, G.E. Albores, P. Slep, L.D. Coe, B.J. Timpson, C.J. Baraldo, L.M. Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| author_facet |
Pieslinger, G.E. Albores, P. Slep, L.D. Coe, B.J. Timpson, C.J. Baraldo, L.M. |
| author_sort |
Pieslinger, G.E. |
| title |
Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| title_short |
Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| title_full |
Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| title_fullStr |
Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| title_full_unstemmed |
Communication between remote moieties in linear Ru-Ru-Ru trimetallic cyanide-bridged complexes |
| title_sort |
communication between remote moieties in linear ru-ru-ru trimetallic cyanide-bridged complexes |
| url |
http://hdl.handle.net/20.500.12110/paper_00201669_v52_n6_p2906_Pieslinger |
| work_keys_str_mv |
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| _version_ |
1807317330162614272 |