Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue
Reaction of trans-Ru(DMSO)4Cl2 with DMAP (DMAP = 4-dimethylaminopyridine) yields the yellow [Ru(DMAP)6]2+ cation in good yield. The crystal and molecular structure of [Ru(DMAP) 6]Cl2·6CH3CH2OH was determined by X-ray diffraction methods. The complex crystallizes in the trigonal R3 space group with a...
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todo:paper_00201669_v47_n7_p2416_Rossi2023-10-03T14:17:00Z Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue Rossi, M.B. Piro, O.E. Castellano, E.E. Alborés, P. Baraldo, L.M. Reaction of trans-Ru(DMSO)4Cl2 with DMAP (DMAP = 4-dimethylaminopyridine) yields the yellow [Ru(DMAP)6]2+ cation in good yield. The crystal and molecular structure of [Ru(DMAP) 6]Cl2·6CH3CH2OH was determined by X-ray diffraction methods. The complex crystallizes in the trigonal R3 space group with a = b = 16.373(1), c = 20.311(1) Å, γ = 120°, and Z = 3 molecules per unit cell. The reaction of [Ru(DMAP) 6]2+ in aerobic water gives the red [Ru III(DMAP)5(OH)]2+ cation. This complex shows a chemical behavior similar to [RuIII(NH3) 5Cl]2+ and allows the preparation of a family of [Ru(DMAP)5L]n+ complexes. Their electronic properties indicate that the {RuIII(DMAP)5} fragment is a weaker π-donor than {RuIII(NH3)5}. Our density functional theory (DFT) calculations show that in {RuII(DMAP) 5} the DMAP ligands can compete for the π electron density of the ruthenium making the fragment a weaker π-donor. © 2008 American Chemical Society. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201669_v47_n7_p2416_Rossi |
| institution |
Universidad de Buenos Aires |
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I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
Reaction of trans-Ru(DMSO)4Cl2 with DMAP (DMAP = 4-dimethylaminopyridine) yields the yellow [Ru(DMAP)6]2+ cation in good yield. The crystal and molecular structure of [Ru(DMAP) 6]Cl2·6CH3CH2OH was determined by X-ray diffraction methods. The complex crystallizes in the trigonal R3 space group with a = b = 16.373(1), c = 20.311(1) Å, γ = 120°, and Z = 3 molecules per unit cell. The reaction of [Ru(DMAP) 6]2+ in aerobic water gives the red [Ru III(DMAP)5(OH)]2+ cation. This complex shows a chemical behavior similar to [RuIII(NH3) 5Cl]2+ and allows the preparation of a family of [Ru(DMAP)5L]n+ complexes. Their electronic properties indicate that the {RuIII(DMAP)5} fragment is a weaker π-donor than {RuIII(NH3)5}. Our density functional theory (DFT) calculations show that in {RuII(DMAP) 5} the DMAP ligands can compete for the π electron density of the ruthenium making the fragment a weaker π-donor. © 2008 American Chemical Society. |
| format |
JOUR |
| author |
Rossi, M.B. Piro, O.E. Castellano, E.E. Alborés, P. Baraldo, L.M. |
| spellingShingle |
Rossi, M.B. Piro, O.E. Castellano, E.E. Alborés, P. Baraldo, L.M. Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| author_facet |
Rossi, M.B. Piro, O.E. Castellano, E.E. Alborés, P. Baraldo, L.M. |
| author_sort |
Rossi, M.B. |
| title |
Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| title_short |
Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| title_full |
Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| title_fullStr |
Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| title_full_unstemmed |
Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue |
| title_sort |
reactivity and spectroscopy of the {ru(dmap)5} fragment: an {ru(nh3)5} analogue |
| url |
http://hdl.handle.net/20.500.12110/paper_00201669_v47_n7_p2416_Rossi |
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1807316722800132096 |