Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]

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The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility...

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Autores principales: Rizzi, A., Baggio, R., Calvo, R., Garland, M.T., Peña, O., Perec, M.
Formato: JOUR
Materias:
gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00201669_v40_n14_p3623_Rizzi
record_format dspace
spelling todo:paper_00201669_v40_n14_p3623_Rizzi2023-10-03T14:16:50Z Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] Rizzi, A. Baggio, R. Calvo, R. Garland, M.T. Peña, O. Perec, M. gadolinium ligand article complex formation crystal structure magnetism molecular dynamics stereochemistry synthesis X ray crystallography The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility and EPR measurements showed weak magnetic exchange coupling of the 3D type. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
spellingShingle gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
Rizzi, A.
Baggio, R.
Calvo, R.
Garland, M.T.
Peña, O.
Perec, M.
Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
topic_facet gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
description The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility and EPR measurements showed weak magnetic exchange coupling of the 3D type.
format JOUR
author Rizzi, A.
Baggio, R.
Calvo, R.
Garland, M.T.
Peña, O.
Perec, M.
author_facet Rizzi, A.
Baggio, R.
Calvo, R.
Garland, M.T.
Peña, O.
Perec, M.
author_sort Rizzi, A.
title Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_short Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_full Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_fullStr Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_full_unstemmed Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_sort synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [gd(cf3co2)3(phen)2 (h2o)]
url http://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi
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AT baggior synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
AT calvor synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
AT garlandmt synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
AT penao synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
AT perecm synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
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