In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals
The possible use of Raman spectroscopy for studies of anodic corrosion film formation on Fe-Cr and Fe-Cr-Mo single crystals has been elucidated. The study shows that Raman spectra from passive films (thickness range 5–6 nm) and from “transpassive films” or films grown during secondary passivity (thi...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00134651_v135_n2_p305_Pallotta |
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todo:paper_00134651_v135_n2_p305_Pallotta2023-10-03T14:10:42Z In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals Pallotta, C. Persson, D. Leygraf, C. CORROSION - Thin Films FILMS - Spectroscopic Analysis MICROANALYSIS SPECTROSCOPY, RAMAN - Applications SPECTROSCOPY, X-RAY - Applications ANODIZING METALLIC STATES NUCLEAR MICROANALYSIS PASSIVE FILMS PHOTOELECTRON ANALYZER IRON CHROMIUM ALLOYS The possible use of Raman spectroscopy for studies of anodic corrosion film formation on Fe-Cr and Fe-Cr-Mo single crystals has been elucidated. The study shows that Raman spectra from passive films (thickness range 5–6 nm) and from “transpassive films” or films grown during secondary passivity (thickness range 5–25 nm) can be detected and interpreted. The results from Raman spectroscopy have been obtained in 1M KOH and combined with complementary results from x-ray photoelectron spectroscopy and nuclear microanalysis. Identified phases in the passive film are a-(Fe, Cr) 2 0 3 and in the transpassive film a-(Fe, Cr) 2 O 3 Fe-Cr spinel, and amorphous FeOOH. © 1988, The Electrochemical Society, Inc. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00134651_v135_n2_p305_Pallotta |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
CORROSION - Thin Films FILMS - Spectroscopic Analysis MICROANALYSIS SPECTROSCOPY, RAMAN - Applications SPECTROSCOPY, X-RAY - Applications ANODIZING METALLIC STATES NUCLEAR MICROANALYSIS PASSIVE FILMS PHOTOELECTRON ANALYZER IRON CHROMIUM ALLOYS |
| spellingShingle |
CORROSION - Thin Films FILMS - Spectroscopic Analysis MICROANALYSIS SPECTROSCOPY, RAMAN - Applications SPECTROSCOPY, X-RAY - Applications ANODIZING METALLIC STATES NUCLEAR MICROANALYSIS PASSIVE FILMS PHOTOELECTRON ANALYZER IRON CHROMIUM ALLOYS Pallotta, C. Persson, D. Leygraf, C. In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals |
| topic_facet |
CORROSION - Thin Films FILMS - Spectroscopic Analysis MICROANALYSIS SPECTROSCOPY, RAMAN - Applications SPECTROSCOPY, X-RAY - Applications ANODIZING METALLIC STATES NUCLEAR MICROANALYSIS PASSIVE FILMS PHOTOELECTRON ANALYZER IRON CHROMIUM ALLOYS |
| description |
The possible use of Raman spectroscopy for studies of anodic corrosion film formation on Fe-Cr and Fe-Cr-Mo single crystals has been elucidated. The study shows that Raman spectra from passive films (thickness range 5–6 nm) and from “transpassive films” or films grown during secondary passivity (thickness range 5–25 nm) can be detected and interpreted. The results from Raman spectroscopy have been obtained in 1M KOH and combined with complementary results from x-ray photoelectron spectroscopy and nuclear microanalysis. Identified phases in the passive film are a-(Fe, Cr) 2 0 3 and in the transpassive film a-(Fe, Cr) 2 O 3 Fe-Cr spinel, and amorphous FeOOH. © 1988, The Electrochemical Society, Inc. All rights reserved. |
| format |
JOUR |
| author |
Pallotta, C. Persson, D. Leygraf, C. |
| author_facet |
Pallotta, C. Persson, D. Leygraf, C. |
| author_sort |
Pallotta, C. |
| title |
In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals |
| title_short |
In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals |
| title_full |
In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals |
| title_fullStr |
In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals |
| title_full_unstemmed |
In-Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals |
| title_sort |
in-situ raman spectroscopy combined with x-ray photoelectron spectroscopy and nuclear microanalysis for studies of anodic corrosion film formation on fe-cr single crystals |
| url |
http://hdl.handle.net/20.500.12110/paper_00134651_v135_n2_p305_Pallotta |
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