Synthetically useful metal-mediated radical transformations in water and aqueous media

In this review non-carbon-centered radicals are used in water and aqueous mixtures to induce and accomplish several synthetically useful organic transformations such as Reformatsky reactions, alkylation and allylation reactions of carbonyl compounds, electron deficient alkenes and imine derivatives,...

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Detalles Bibliográficos
Autores principales:	Postigo, A., Nudelman, N.S.
Formato:	JOUR
Materias:	Metal radicals in water Metal-mediated radical alkylation and allylation reactions in water Metal-mediated radical cyclizations in water Metal-mediated radical reductions and oxidations in water Metal-mediated reductive cross coupling in water
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00108545_v255_n23-24_p2991_Postigo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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spelling	todo:paper_00108545_v255_n23-24_p2991_Postigo2023-10-03T14:09:31Z Synthetically useful metal-mediated radical transformations in water and aqueous media Postigo, A. Nudelman, N.S. Metal radicals in water Metal-mediated radical alkylation and allylation reactions in water Metal-mediated radical cyclizations in water Metal-mediated radical reductions and oxidations in water Metal-mediated reductive cross coupling in water In this review non-carbon-centered radicals are used in water and aqueous mixtures to induce and accomplish several synthetically useful organic transformations such as Reformatsky reactions, alkylation and allylation reactions of carbonyl compounds, electron deficient alkenes and imine derivatives, radical conjugate additions, metal-mediated radical cyclizations, reductive cross coupling reactions and other coupling reactions, oxidation and reduction reactions in water. In doing so, the array of metal radicals used encompass elements from the main groups (IIIB, IVB, VB and VIB groups), as well as transition metals. However, the important class of radical hydrometallation reactions of carbon-carbon multiple bonds in water is not the subject of this work. © 2011 Elsevier B.V. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00108545_v255_n23-24_p2991_Postigo
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Metal radicals in water Metal-mediated radical alkylation and allylation reactions in water Metal-mediated radical cyclizations in water Metal-mediated radical reductions and oxidations in water Metal-mediated reductive cross coupling in water
spellingShingle	Metal radicals in water Metal-mediated radical alkylation and allylation reactions in water Metal-mediated radical cyclizations in water Metal-mediated radical reductions and oxidations in water Metal-mediated reductive cross coupling in water Postigo, A. Nudelman, N.S. Synthetically useful metal-mediated radical transformations in water and aqueous media
topic_facet	Metal radicals in water Metal-mediated radical alkylation and allylation reactions in water Metal-mediated radical cyclizations in water Metal-mediated radical reductions and oxidations in water Metal-mediated reductive cross coupling in water
description	In this review non-carbon-centered radicals are used in water and aqueous mixtures to induce and accomplish several synthetically useful organic transformations such as Reformatsky reactions, alkylation and allylation reactions of carbonyl compounds, electron deficient alkenes and imine derivatives, radical conjugate additions, metal-mediated radical cyclizations, reductive cross coupling reactions and other coupling reactions, oxidation and reduction reactions in water. In doing so, the array of metal radicals used encompass elements from the main groups (IIIB, IVB, VB and VIB groups), as well as transition metals. However, the important class of radical hydrometallation reactions of carbon-carbon multiple bonds in water is not the subject of this work. © 2011 Elsevier B.V.
format	JOUR
author	Postigo, A. Nudelman, N.S.
author_facet	Postigo, A. Nudelman, N.S.
author_sort	Postigo, A.
title	Synthetically useful metal-mediated radical transformations in water and aqueous media
title_short	Synthetically useful metal-mediated radical transformations in water and aqueous media
title_full	Synthetically useful metal-mediated radical transformations in water and aqueous media
title_fullStr	Synthetically useful metal-mediated radical transformations in water and aqueous media
title_full_unstemmed	Synthetically useful metal-mediated radical transformations in water and aqueous media
title_sort	synthetically useful metal-mediated radical transformations in water and aqueous media
url	http://hdl.handle.net/20.500.12110/paper_00108545_v255_n23-24_p2991_Postigo
work_keys_str_mv	AT postigoa syntheticallyusefulmetalmediatedradicaltransformationsinwaterandaqueousmedia AT nudelmanns syntheticallyusefulmetalmediatedradicaltransformationsinwaterandaqueousmedia
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Synthetically useful metal-mediated radical transformations in water and aqueous media

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