The reaction of ammonia with acetyl derivatives of gentiobiose

The reaction of aqueous ammonia with octa-O-acetylgentiobiose gives 1,1-bis-(acetamido)-1-deoxy-6-O-β-D-glucopyranosyl-D-glucitol (1) and N-acetyl-6-O-β-D-glucopyranosyl-β-D-glucofuranosylamine (3). The structure of the furanoid compound 3 was demonstrated by methylation and hydrolysis techniques, a...

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Autores principales: Zanlungo, A.B., Defferrari, J.O., Gelpi, M.E., Cadenas, R.A.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v35_n1_p33_Zanlungo
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_00086215_v35_n1_p33_Zanlungo2023-10-03T14:07:30Z The reaction of ammonia with acetyl derivatives of gentiobiose Zanlungo, A.B. Defferrari, J.O. Gelpi, M.E. Cadenas, R.A. The reaction of aqueous ammonia with octa-O-acetylgentiobiose gives 1,1-bis-(acetamido)-1-deoxy-6-O-β-D-glucopyranosyl-D-glucitol (1) and N-acetyl-6-O-β-D-glucopyranosyl-β-D-glucofuranosylamine (3). The structure of the furanoid compound 3 was demonstrated by methylation and hydrolysis techniques, and its anomeric configuration through periodate oxidation and borohydride reduction. © 1974. Fil:Zanlungo, A.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gelpi, M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cadenas, R.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v35_n1_p33_Zanlungo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The reaction of aqueous ammonia with octa-O-acetylgentiobiose gives 1,1-bis-(acetamido)-1-deoxy-6-O-β-D-glucopyranosyl-D-glucitol (1) and N-acetyl-6-O-β-D-glucopyranosyl-β-D-glucofuranosylamine (3). The structure of the furanoid compound 3 was demonstrated by methylation and hydrolysis techniques, and its anomeric configuration through periodate oxidation and borohydride reduction. © 1974.
format JOUR
author Zanlungo, A.B.
Defferrari, J.O.
Gelpi, M.E.
Cadenas, R.A.
spellingShingle Zanlungo, A.B.
Defferrari, J.O.
Gelpi, M.E.
Cadenas, R.A.
The reaction of ammonia with acetyl derivatives of gentiobiose
author_facet Zanlungo, A.B.
Defferrari, J.O.
Gelpi, M.E.
Cadenas, R.A.
author_sort Zanlungo, A.B.
title The reaction of ammonia with acetyl derivatives of gentiobiose
title_short The reaction of ammonia with acetyl derivatives of gentiobiose
title_full The reaction of ammonia with acetyl derivatives of gentiobiose
title_fullStr The reaction of ammonia with acetyl derivatives of gentiobiose
title_full_unstemmed The reaction of ammonia with acetyl derivatives of gentiobiose
title_sort reaction of ammonia with acetyl derivatives of gentiobiose
url http://hdl.handle.net/20.500.12110/paper_00086215_v35_n1_p33_Zanlungo
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