Benzoyl derivatives of d-gluconolactones and their reaction with alcohols

Benzoylation of d-glucono-1,4-lactone and d-glucono-1,5-lactone afforded the corresponding tetra-O-benzoyl derivatives. They showed the optical rotation and i.r. spectral absorption characteristic for 1,4 or 1,5-lactones, respectively. Opening of the lactone ring was effected by treatment with alcoh...

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Autores principales: de Lederkremer, R.M., Fernández Cirelli, A., Deferrari, J.O.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v13_n1_p9_deLederkremer
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00086215_v13_n1_p9_deLederkremer
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spelling todo:paper_00086215_v13_n1_p9_deLederkremer2023-10-03T14:06:20Z Benzoyl derivatives of d-gluconolactones and their reaction with alcohols de Lederkremer, R.M. Fernández Cirelli, A. Deferrari, J.O. Benzoylation of d-glucono-1,4-lactone and d-glucono-1,5-lactone afforded the corresponding tetra-O-benzoyl derivatives. They showed the optical rotation and i.r. spectral absorption characteristic for 1,4 or 1,5-lactones, respectively. Opening of the lactone ring was effected by treatment with alcohols to give tetra-O-benzoyl-d-gluconates having an unesterified hydroxyl group at C-4 or C-5, respectively. © 1970. Fil:de Lederkremer, R.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernández Cirelli, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v13_n1_p9_deLederkremer
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Benzoylation of d-glucono-1,4-lactone and d-glucono-1,5-lactone afforded the corresponding tetra-O-benzoyl derivatives. They showed the optical rotation and i.r. spectral absorption characteristic for 1,4 or 1,5-lactones, respectively. Opening of the lactone ring was effected by treatment with alcohols to give tetra-O-benzoyl-d-gluconates having an unesterified hydroxyl group at C-4 or C-5, respectively. © 1970.
format JOUR
author de Lederkremer, R.M.
Fernández Cirelli, A.
Deferrari, J.O.
spellingShingle de Lederkremer, R.M.
Fernández Cirelli, A.
Deferrari, J.O.
Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
author_facet de Lederkremer, R.M.
Fernández Cirelli, A.
Deferrari, J.O.
author_sort de Lederkremer, R.M.
title Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
title_short Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
title_full Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
title_fullStr Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
title_full_unstemmed Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
title_sort benzoyl derivatives of d-gluconolactones and their reaction with alcohols
url http://hdl.handle.net/20.500.12110/paper_00086215_v13_n1_p9_deLederkremer
work_keys_str_mv AT delederkremerrm benzoylderivativesofdgluconolactonesandtheirreactionwithalcohols
AT fernandezcirellia benzoylderivativesofdgluconolactonesandtheirreactionwithalcohols
AT deferrarijo benzoylderivativesofdgluconolactonesandtheirreactionwithalcohols
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