Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine
The conformational and steric factors that determine the different contributions of the acyl groups to the formation of 1,1-bis(acylamido)-1-deoxyalditols by the ammonolysis of acyl esters of carbohydrates of different structures are discussed. The isolation and structure of N-acetyl β-D-galactofura...
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todo:paper_00086215_v10_n3_p403_BZanlungo2023-10-03T14:06:15Z Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine B. Zanlungo, A. O. Deferrari, J. A. Cadenas, R. The conformational and steric factors that determine the different contributions of the acyl groups to the formation of 1,1-bis(acylamido)-1-deoxyalditols by the ammonolysis of acyl esters of carbohydrates of different structures are discussed. The isolation and structure of N-acetyl β-D-galactofuranosylamine, obtained by such a reaction, are reported, and the conformation of this sugar and that of the N-acetyl-α-D-glucofuranosylamine previously described are considered on the basis of n.m.r. data. © 1969. Fil:B. Zanlungo, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:O. Deferrari, J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:A. Cadenas, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v10_n3_p403_BZanlungo |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
The conformational and steric factors that determine the different contributions of the acyl groups to the formation of 1,1-bis(acylamido)-1-deoxyalditols by the ammonolysis of acyl esters of carbohydrates of different structures are discussed. The isolation and structure of N-acetyl β-D-galactofuranosylamine, obtained by such a reaction, are reported, and the conformation of this sugar and that of the N-acetyl-α-D-glucofuranosylamine previously described are considered on the basis of n.m.r. data. © 1969. |
format |
JOUR |
author |
B. Zanlungo, A. O. Deferrari, J. A. Cadenas, R. |
spellingShingle |
B. Zanlungo, A. O. Deferrari, J. A. Cadenas, R. Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine |
author_facet |
B. Zanlungo, A. O. Deferrari, J. A. Cadenas, R. |
author_sort |
B. Zanlungo, A. |
title |
Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine |
title_short |
Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine |
title_full |
Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine |
title_fullStr |
Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine |
title_full_unstemmed |
Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine |
title_sort |
acyl migrations in acylated monosaccharides. formation of n-acetyl-β-d-galactofuranosylamine |
url |
http://hdl.handle.net/20.500.12110/paper_00086215_v10_n3_p403_BZanlungo |
work_keys_str_mv |
AT bzanlungoa acylmigrationsinacylatedmonosaccharidesformationofnacetylbdgalactofuranosylamine AT odeferrarij acylmigrationsinacylatedmonosaccharidesformationofnacetylbdgalactofuranosylamine AT acadenasr acylmigrationsinacylatedmonosaccharidesformationofnacetylbdgalactofuranosylamine |
_version_ |
1807321085587226624 |