Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions

Soft (SS) and hard (HS) stearins obtained from high-oleic high-stearic sunflower oil were isothermally crystallized under dynamic (with agitation) and static conditions at 16, 17, 18, 19, and 20 C and 24, 25, 26, 27, and 28 C, respectively. Both fractions crystallized under the α-form at early stage...

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Detalles Bibliográficos
Autores principales: Martini, S., Cardona, J.A.R., Ye, Y., Tan, C.Y., Candal, R.J., Herrera, M.L.
Formato: JOUR
Materias:
Crystallization
Fats
High stearic high oleic sunflower oil
Morphology
Polymorphism
Texture
Thermal behavior
Crystallization behavior
Dynamic condition
High-oleic sunflower oil
Polymorphic behavior
Shear conditions
Static conditions
Tempering temperature
Thermal behaviors
Oils and fats
Textures
Helianthus
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_0003021X_v90_n12_p1773_Martini
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_0003021X_v90_n12_p1773_Martini
record_format dspace
spelling todo:paper_0003021X_v90_n12_p1773_Martini2023-10-03T13:55:36Z Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions Martini, S. Cardona, J.A.R. Ye, Y. Tan, C.Y. Candal, R.J. Herrera, M.L. Crystallization Fats High stearic high oleic sunflower oil Morphology Polymorphism Texture Thermal behavior Crystallization behavior Dynamic condition High-oleic sunflower oil Polymorphic behavior Shear conditions Static conditions Tempering temperature Thermal behaviors Crystallization Morphology Oils and fats Textures Polymorphism Helianthus Soft (SS) and hard (HS) stearins obtained from high-oleic high-stearic sunflower oil were isothermally crystallized under dynamic (with agitation) and static conditions at 16, 17, 18, 19, and 20 C and 24, 25, 26, 27, and 28 C, respectively. Both fractions crystallized under the α-form at early stages of crystallization for all temperatures (T c) tested. Polymorphic behavior strongly changed with T c and shear conditions for both fractions. SS fractions were characterized by α, β2 and/or β1 polymorphs at lower T c and β1 crystals at higher T c when crystallized under dynamic conditions, while this same fat system was characterized by β2′ crystals at lower T c and β2 at higher T c under static conditions. HS samples were mainly characterized by α and β2 crystals at lower T c and α and β1 crystals at higher T c when crystallized under dynamic conditions; while the same fat was characterized by β 1′ crystals when crystallized at lower T c and α when crystallized at higher T c under static conditions after 90 min at T c. These different polymorphic behaviors, in combination with the different processing and tempering temperatures are translated in specific textural behavior of the samples. © 2013 AOCS. Fil:Candal, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_0003021X_v90_n12_p1773_Martini
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Crystallization
Fats
High stearic high oleic sunflower oil
Morphology
Polymorphism
Texture
Thermal behavior
Crystallization behavior
Dynamic condition
High-oleic sunflower oil
Polymorphic behavior
Shear conditions
Static conditions
Tempering temperature
Thermal behaviors
Crystallization
Morphology
Oils and fats
Textures
Polymorphism
Helianthus
spellingShingle Crystallization
Fats
High stearic high oleic sunflower oil
Morphology
Polymorphism
Texture
Thermal behavior
Crystallization behavior
Dynamic condition
High-oleic sunflower oil
Polymorphic behavior
Shear conditions
Static conditions
Tempering temperature
Thermal behaviors
Crystallization
Morphology
Oils and fats
Textures
Polymorphism
Helianthus
Martini, S.
Cardona, J.A.R.
Ye, Y.
Tan, C.Y.
Candal, R.J.
Herrera, M.L.
Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
topic_facet Crystallization
Fats
High stearic high oleic sunflower oil
Morphology
Polymorphism
Texture
Thermal behavior
Crystallization behavior
Dynamic condition
High-oleic sunflower oil
Polymorphic behavior
Shear conditions
Static conditions
Tempering temperature
Thermal behaviors
Crystallization
Morphology
Oils and fats
Textures
Polymorphism
Helianthus
description Soft (SS) and hard (HS) stearins obtained from high-oleic high-stearic sunflower oil were isothermally crystallized under dynamic (with agitation) and static conditions at 16, 17, 18, 19, and 20 C and 24, 25, 26, 27, and 28 C, respectively. Both fractions crystallized under the α-form at early stages of crystallization for all temperatures (T c) tested. Polymorphic behavior strongly changed with T c and shear conditions for both fractions. SS fractions were characterized by α, β2 and/or β1 polymorphs at lower T c and β1 crystals at higher T c when crystallized under dynamic conditions, while this same fat system was characterized by β2′ crystals at lower T c and β2 at higher T c under static conditions. HS samples were mainly characterized by α and β2 crystals at lower T c and α and β1 crystals at higher T c when crystallized under dynamic conditions; while the same fat was characterized by β 1′ crystals when crystallized at lower T c and α when crystallized at higher T c under static conditions after 90 min at T c. These different polymorphic behaviors, in combination with the different processing and tempering temperatures are translated in specific textural behavior of the samples. © 2013 AOCS.
format JOUR
author Martini, S.
Cardona, J.A.R.
Ye, Y.
Tan, C.Y.
Candal, R.J.
Herrera, M.L.
author_facet Martini, S.
Cardona, J.A.R.
Ye, Y.
Tan, C.Y.
Candal, R.J.
Herrera, M.L.
author_sort Martini, S.
title Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
title_short Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
title_full Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
title_fullStr Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
title_full_unstemmed Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
title_sort crystallization behavior of high-oleic high-stearic sunflower oil stearins under dynamic and static conditions
url http://hdl.handle.net/20.500.12110/paper_0003021X_v90_n12_p1773_Martini
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AT tancy crystallizationbehaviorofhigholeichighstearicsunfloweroilstearinsunderdynamicandstaticconditions
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