A surprisingly stable S-nitrosothiol complex
In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti |
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todo:paper_00027863_v128_n8_p2512_Perissinotti2023-10-03T13:53:52Z A surprisingly stable S-nitrosothiol complex Perissinotti, L.L. Estrin, D.A. Leitus, G. Doctorovich, F. s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated. Copyright © 2006 American Chemical Society. Fil:Perissinotti, L.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Estrin, D.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti |
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Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis |
| spellingShingle |
s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis Perissinotti, L.L. Estrin, D.A. Leitus, G. Doctorovich, F. A surprisingly stable S-nitrosothiol complex |
| topic_facet |
s nitrosothiol article complex formation crystal structure density functional theory infrared spectroscopy proton nuclear magnetic resonance synthesis |
| description |
In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated. Copyright © 2006 American Chemical Society. |
| format |
JOUR |
| author |
Perissinotti, L.L. Estrin, D.A. Leitus, G. Doctorovich, F. |
| author_facet |
Perissinotti, L.L. Estrin, D.A. Leitus, G. Doctorovich, F. |
| author_sort |
Perissinotti, L.L. |
| title |
A surprisingly stable S-nitrosothiol complex |
| title_short |
A surprisingly stable S-nitrosothiol complex |
| title_full |
A surprisingly stable S-nitrosothiol complex |
| title_fullStr |
A surprisingly stable S-nitrosothiol complex |
| title_full_unstemmed |
A surprisingly stable S-nitrosothiol complex |
| title_sort |
surprisingly stable s-nitrosothiol complex |
| url |
http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti |
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| _version_ |
1807314877629333504 |