Molecular "wiring" enzymes in organized nanostructures

We report on the "molecular wiring" efficiency of glucose oxidase in organized self-assembled nanostructures comprised of enzyme layers alternating with layers of an osmium-derivatized poly(allylamine) cationic polyelectrolyte, acting as redox relays. Varying the relative position of the a...

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Detalles Bibliográficos
Autores principales:	Calvo, E.J., Danilowicz, C., Wolosiuk, A.
Formato:	JOUR
Materias:	apoenzyme avidin biotin enzyme glucose glucose oxidase osmium polyelectrolyte polymer single stranded DNA adsorption amperometry antigen antibody reaction article biosensor cyclic potentiometry diffusion diffusion coefficient DNA hybridization electricity electrochemical analysis electron transport electronics enzyme immobilization enzyme structure glucose oxidation hydrogel isoelectric point Michaelis constant molecular recognition oxidation pH steady state Electrochemistry Glucose Glucose Oxidase Nanotechnology Organometallic Compounds Osmium Oxidation-Reduction Pyridines
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00027863_v124_n11_p2452_Calvo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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