Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate

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The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyri...

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Detalles Bibliográficos
Autores principales: Baggio, R., Perec, M., Garland, M.T.
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: 1996
Materias:
Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_Baggio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paperaa:paper_01082701_v52_n10_p2457_Baggio2023-06-12T16:46:31Z Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate Acta Crystallogr Sect C Cryst Struct Commun 1996;52(10):2457-2460 Baggio, R. Perec, M. Garland, M.T. Crystal atomic structure Crystal defects Crystallography Hydrogen bonds Molecular structure Zinc compounds Aqua ligands Octahedral coordination geometry Tridentate thiodiacetate ligand Organometallics The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1996 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion application/pdf eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
language Inglés
orig_language_str_mv eng
topic Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
spellingShingle Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
Baggio, R.
Perec, M.
Garland, M.T.
Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
topic_facet Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
description The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.
format Artículo
Artículo
publishedVersion
author Baggio, R.
Perec, M.
Garland, M.T.
author_facet Baggio, R.
Perec, M.
Garland, M.T.
author_sort Baggio, R.
title Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_short Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_full Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_fullStr Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_full_unstemmed Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_sort aqua(2,2′-bipyridyl-n,n′)(thiodiacetato-0,0′,s)zinc(ii) tetrahydrate
publishDate 1996
url http://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_Baggio
work_keys_str_mv AT baggior aqua22bipyridylnnthiodiacetato00szinciitetrahydrate
AT perecm aqua22bipyridylnnthiodiacetato00szinciitetrahydrate
AT garlandmt aqua22bipyridylnnthiodiacetato00szinciitetrahydrate
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