Solvation dynamics following electron photodetachment from l- in aqueous clusters

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New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the micr...

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Detalles Bibliográficos
Autores principales: Elola, M.D., Laria, D.
Formato: Artículo publishedVersion
Lenguaje:Inglés
Publicado: 2002
Materias:
Algorithms
Chemical relaxation
Diffusion
Electronic properties
Ground state
Mathematical models
Molecular structure
Photochemical reactions
Quantum theory
Solutions
Diffuse density profile
Electron photodetachment
Electronic excitation
Equilibrium solvation structures
Solvation dynamics
Surface states
Molecular dynamics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe.

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