Solvation dynamics following electron photodetachment from l- in aqueous clusters
New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the micr...
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2002
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola |
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paperaa:paper_00219606_v117_n5_p2238_Elola2023-06-12T16:43:09Z Solvation dynamics following electron photodetachment from l- in aqueous clusters J Chem Phys 2002;117(5):2238-2245 Elola, M.D. Laria, D. Algorithms Chemical relaxation Diffusion Electronic properties Ground state Mathematical models Molecular structure Photochemical reactions Quantum theory Solutions Diffuse density profile Electron photodetachment Electronic excitation Equilibrium solvation structures Solvation dynamics Surface states Molecular dynamics New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe. Fil:Elola, M.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Laria, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2002 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion application/pdf eng info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
language |
Inglés |
orig_language_str_mv |
eng |
topic |
Algorithms Chemical relaxation Diffusion Electronic properties Ground state Mathematical models Molecular structure Photochemical reactions Quantum theory Solutions Diffuse density profile Electron photodetachment Electronic excitation Equilibrium solvation structures Solvation dynamics Surface states Molecular dynamics |
spellingShingle |
Algorithms Chemical relaxation Diffusion Electronic properties Ground state Mathematical models Molecular structure Photochemical reactions Quantum theory Solutions Diffuse density profile Electron photodetachment Electronic excitation Equilibrium solvation structures Solvation dynamics Surface states Molecular dynamics Elola, M.D. Laria, D. Solvation dynamics following electron photodetachment from l- in aqueous clusters |
topic_facet |
Algorithms Chemical relaxation Diffusion Electronic properties Ground state Mathematical models Molecular structure Photochemical reactions Quantum theory Solutions Diffuse density profile Electron photodetachment Electronic excitation Equilibrium solvation structures Solvation dynamics Surface states Molecular dynamics |
description |
New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe. |
format |
Artículo Artículo publishedVersion |
author |
Elola, M.D. Laria, D. |
author_facet |
Elola, M.D. Laria, D. |
author_sort |
Elola, M.D. |
title |
Solvation dynamics following electron photodetachment from l- in aqueous clusters |
title_short |
Solvation dynamics following electron photodetachment from l- in aqueous clusters |
title_full |
Solvation dynamics following electron photodetachment from l- in aqueous clusters |
title_fullStr |
Solvation dynamics following electron photodetachment from l- in aqueous clusters |
title_full_unstemmed |
Solvation dynamics following electron photodetachment from l- in aqueous clusters |
title_sort |
solvation dynamics following electron photodetachment from l- in aqueous clusters |
publishDate |
2002 |
url |
http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola |
work_keys_str_mv |
AT elolamd solvationdynamicsfollowingelectronphotodetachmentfromlinaqueousclusters AT lariad solvationdynamicsfollowingelectronphotodetachmentfromlinaqueousclusters |
_version_ |
1769810082963390464 |