Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles

Direct evidence is presented that the otherwise thermodynamically forbidden reduction of As(V) by conduction band electrons of the semiconductor can be driven in the dark by accumulated electrons stored in alcoholic TiO2 nanoparticles. Accumulation of electrons and participation in As(V) reduction w...

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Detalles Bibliográficos
Autores principales: Levy, Ivana Karina, Litter, Marta Irene, San Roman, Enrique Arnoldo
Publicado: 2014
Materias:
TiO
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97811380_v_n_p802_Levy
http://hdl.handle.net/20.500.12110/paper_97811380_v_n_p802_Levy
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spelling paper:paper_97811380_v_n_p802_Levy2023-06-08T16:37:17Z Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles Levy, Ivana Karina Litter, Marta Irene San Roman, Enrique Arnoldo Arsenic Magnetic resonance Nanoparticles Conduction band electrons TiO TiO2 nano-particles UV-vis spectrophotometry Electrons Direct evidence is presented that the otherwise thermodynamically forbidden reduction of As(V) by conduction band electrons of the semiconductor can be driven in the dark by accumulated electrons stored in alcoholic TiO2 nanoparticles. Accumulation of electrons and participation in As(V) reduction was directly followed by UV-vis spectrophotometry and by Electron Paramagnetic Resonance, detected as Ti(III) species. © 2014 Taylor & Francis Group. Fil:Levy, I.K. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Litter, M.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:San Román, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2014 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97811380_v_n_p802_Levy http://hdl.handle.net/20.500.12110/paper_97811380_v_n_p802_Levy
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Arsenic
Magnetic resonance
Nanoparticles
Conduction band electrons
TiO
TiO2 nano-particles
UV-vis spectrophotometry
Electrons
spellingShingle Arsenic
Magnetic resonance
Nanoparticles
Conduction band electrons
TiO
TiO2 nano-particles
UV-vis spectrophotometry
Electrons
Levy, Ivana Karina
Litter, Marta Irene
San Roman, Enrique Arnoldo
Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
topic_facet Arsenic
Magnetic resonance
Nanoparticles
Conduction band electrons
TiO
TiO2 nano-particles
UV-vis spectrophotometry
Electrons
description Direct evidence is presented that the otherwise thermodynamically forbidden reduction of As(V) by conduction band electrons of the semiconductor can be driven in the dark by accumulated electrons stored in alcoholic TiO2 nanoparticles. Accumulation of electrons and participation in As(V) reduction was directly followed by UV-vis spectrophotometry and by Electron Paramagnetic Resonance, detected as Ti(III) species. © 2014 Taylor & Francis Group.
author Levy, Ivana Karina
Litter, Marta Irene
San Roman, Enrique Arnoldo
author_facet Levy, Ivana Karina
Litter, Marta Irene
San Roman, Enrique Arnoldo
author_sort Levy, Ivana Karina
title Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
title_short Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
title_full Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
title_fullStr Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
title_full_unstemmed Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
title_sort dark reduction of as(v) by accumulated electrons stored in alcoholic tio2 nanoparticles
publishDate 2014
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97811380_v_n_p802_Levy
http://hdl.handle.net/20.500.12110/paper_97811380_v_n_p802_Levy
work_keys_str_mv AT levyivanakarina darkreductionofasvbyaccumulatedelectronsstoredinalcoholictio2nanoparticles
AT littermartairene darkreductionofasvbyaccumulatedelectronsstoredinalcoholictio2nanoparticles
AT sanromanenriquearnoldo darkreductionofasvbyaccumulatedelectronsstoredinalcoholictio2nanoparticles
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