Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion
A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. T...
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2018
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n3_p351_Harvey http://hdl.handle.net/20.500.12110/paper_20532296_v74_n3_p351_Harvey |
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paper:paper_20532296_v74_n3_p351_Harvey2023-06-08T16:34:04Z Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion crystal structure hydrogen-bonded porous structures sulfate bridge topological analysis Complexation Coordination reactions Crystal structure Nickel Nickel sulfates Sulfur compounds Topology Coordination complex Hydrogen-bonded structures Porous structures Reference frameworks Three-dimensional structure Title compounds Topological analysis Topological approach Hydrogen bonds A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches. © International Union of Crystallography, 2018. 2018 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n3_p351_Harvey http://hdl.handle.net/20.500.12110/paper_20532296_v74_n3_p351_Harvey |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
crystal structure hydrogen-bonded porous structures sulfate bridge topological analysis Complexation Coordination reactions Crystal structure Nickel Nickel sulfates Sulfur compounds Topology Coordination complex Hydrogen-bonded structures Porous structures Reference frameworks Three-dimensional structure Title compounds Topological analysis Topological approach Hydrogen bonds |
| spellingShingle |
crystal structure hydrogen-bonded porous structures sulfate bridge topological analysis Complexation Coordination reactions Crystal structure Nickel Nickel sulfates Sulfur compounds Topology Coordination complex Hydrogen-bonded structures Porous structures Reference frameworks Three-dimensional structure Title compounds Topological analysis Topological approach Hydrogen bonds Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
| topic_facet |
crystal structure hydrogen-bonded porous structures sulfate bridge topological analysis Complexation Coordination reactions Crystal structure Nickel Nickel sulfates Sulfur compounds Topology Coordination complex Hydrogen-bonded structures Porous structures Reference frameworks Three-dimensional structure Title compounds Topological analysis Topological approach Hydrogen bonds |
| description |
A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches. © International Union of Crystallography, 2018. |
| title |
Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
| title_short |
Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
| title_full |
Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
| title_fullStr |
Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
| title_full_unstemmed |
Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
| title_sort |
topological study of diverse hydrogen-bonded patterns found in a system of a nickel(ii) complex and the sulfate anion |
| publishDate |
2018 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n3_p351_Harvey http://hdl.handle.net/20.500.12110/paper_20532296_v74_n3_p351_Harvey |
| _version_ |
1768546651520106496 |