Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions:
Among the potential applications of coordination polymers, electrical conductivity ranks high in technological interest. We report the synthesis, crystal structure and spectroscopic analysis of an AgI-thiosaccharinate one-dimensional coordination polymer {systematic name: Catena-poly[[[aquatetrakis(...
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2018
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paper:paper_20532296_v74_n2_p186_Dennehy2023-06-08T16:34:04Z Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: argentophilic interaction electrical propertiescrystal structure low conductivity semiconductor one-dimensional coordination polymer silver(I) polymeric structure Chelation Coordination reactions Crystal atomic structure Dimethyl sulfoxide Electric conductivity Polymers Polyols Propane Silver Silver compounds Spectroscopic analysis Argentophilic interaction Coordination Polymers Electrical conductivity Electrical conductivity measurements Low conductivity Low-frequency spectra One-dimensional coordination polymer Polymeric structures Crystal structure coordination compound ligand polymer saccharin silver analogs and derivatives chemical model chemical structure chemistry electric conductivity quantum theory synthesis X ray crystallography Coordination Complexes Crystallography, X-Ray Electric Conductivity Ligands Models, Chemical Molecular Structure Polymers Quantum Theory Saccharin Silver Among the potential applications of coordination polymers, electrical conductivity ranks high in technological interest. We report the synthesis, crystal structure and spectroscopic analysis of an AgI-thiosaccharinate one-dimensional coordination polymer {systematic name: Catena-poly[[[aquatetrakis(μ3-1,1-dioxo-1,2-benzisothiazole-3-thiolato-κ3N:S3:S3)tetrasilver(I)]-μ2-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N′] dimethyl sulfoxide hemisolvate]}, {[Ag4(C7H4NO2S2)4(C13H14N2)(H2O)]·0.5C2H6OS}n, with the 4,4′-(propane-1,3-diyl)dipyridine ligand acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag.Ag distance of 2.8306'(9)'Å, well within the range of argentophilic interactions, confirmed experimentally as such by a Raman study on the low-frequency spectrum, and corroborated theoretically by an Atoms in Molecules (AIM) analysis of the calculated electron density. Electrical conductivity measurements show that this complex can act as a semiconductor with moderate conductivity.A one-dimensional polymeric silver thiosaccharinate complex displays an unusually short Ag.Ag distance of 2.830Å. The crystal structure consists of weakly interacting columns. The complex behaves as a semiconductor, with a moderately low conductivity. © 2018 International Union of Crystallography. 2018 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n2_p186_Dennehy http://hdl.handle.net/20.500.12110/paper_20532296_v74_n2_p186_Dennehy |
| institution |
Universidad de Buenos Aires |
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I-28 |
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R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
argentophilic interaction electrical propertiescrystal structure low conductivity semiconductor one-dimensional coordination polymer silver(I) polymeric structure Chelation Coordination reactions Crystal atomic structure Dimethyl sulfoxide Electric conductivity Polymers Polyols Propane Silver Silver compounds Spectroscopic analysis Argentophilic interaction Coordination Polymers Electrical conductivity Electrical conductivity measurements Low conductivity Low-frequency spectra One-dimensional coordination polymer Polymeric structures Crystal structure coordination compound ligand polymer saccharin silver analogs and derivatives chemical model chemical structure chemistry electric conductivity quantum theory synthesis X ray crystallography Coordination Complexes Crystallography, X-Ray Electric Conductivity Ligands Models, Chemical Molecular Structure Polymers Quantum Theory Saccharin Silver |
| spellingShingle |
argentophilic interaction electrical propertiescrystal structure low conductivity semiconductor one-dimensional coordination polymer silver(I) polymeric structure Chelation Coordination reactions Crystal atomic structure Dimethyl sulfoxide Electric conductivity Polymers Polyols Propane Silver Silver compounds Spectroscopic analysis Argentophilic interaction Coordination Polymers Electrical conductivity Electrical conductivity measurements Low conductivity Low-frequency spectra One-dimensional coordination polymer Polymeric structures Crystal structure coordination compound ligand polymer saccharin silver analogs and derivatives chemical model chemical structure chemistry electric conductivity quantum theory synthesis X ray crystallography Coordination Complexes Crystallography, X-Ray Electric Conductivity Ligands Models, Chemical Molecular Structure Polymers Quantum Theory Saccharin Silver Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| topic_facet |
argentophilic interaction electrical propertiescrystal structure low conductivity semiconductor one-dimensional coordination polymer silver(I) polymeric structure Chelation Coordination reactions Crystal atomic structure Dimethyl sulfoxide Electric conductivity Polymers Polyols Propane Silver Silver compounds Spectroscopic analysis Argentophilic interaction Coordination Polymers Electrical conductivity Electrical conductivity measurements Low conductivity Low-frequency spectra One-dimensional coordination polymer Polymeric structures Crystal structure coordination compound ligand polymer saccharin silver analogs and derivatives chemical model chemical structure chemistry electric conductivity quantum theory synthesis X ray crystallography Coordination Complexes Crystallography, X-Ray Electric Conductivity Ligands Models, Chemical Molecular Structure Polymers Quantum Theory Saccharin Silver |
| description |
Among the potential applications of coordination polymers, electrical conductivity ranks high in technological interest. We report the synthesis, crystal structure and spectroscopic analysis of an AgI-thiosaccharinate one-dimensional coordination polymer {systematic name: Catena-poly[[[aquatetrakis(μ3-1,1-dioxo-1,2-benzisothiazole-3-thiolato-κ3N:S3:S3)tetrasilver(I)]-μ2-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N′] dimethyl sulfoxide hemisolvate]}, {[Ag4(C7H4NO2S2)4(C13H14N2)(H2O)]·0.5C2H6OS}n, with the 4,4′-(propane-1,3-diyl)dipyridine ligand acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag.Ag distance of 2.8306'(9)'Å, well within the range of argentophilic interactions, confirmed experimentally as such by a Raman study on the low-frequency spectrum, and corroborated theoretically by an Atoms in Molecules (AIM) analysis of the calculated electron density. Electrical conductivity measurements show that this complex can act as a semiconductor with moderate conductivity.A one-dimensional polymeric silver thiosaccharinate complex displays an unusually short Ag.Ag distance of 2.830Å. The crystal structure consists of weakly interacting columns. The complex behaves as a semiconductor, with a moderately low conductivity. © 2018 International Union of Crystallography. |
| title |
Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| title_short |
Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| title_full |
Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| title_fullStr |
Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| title_full_unstemmed |
Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| title_sort |
structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions: |
| publishDate |
2018 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n2_p186_Dennehy http://hdl.handle.net/20.500.12110/paper_20532296_v74_n2_p186_Dennehy |
| _version_ |
1768543581911384064 |