Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate

The title compound, [Dy2(C4H5O 2)6(C12H8N2) 2]·H2O, crystallizes as dimeric units with an inversion center. Each Dy atom is nine-coordinate, by seven O atoms from trans-2-butenoate groups and two N atoms from a phenanthroline molecule. The dimer is quadruply bridged by trans-2-butenoates (two η1: η1...

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Detalles Bibliográficos
Publicado: 2003
Materias:
Characterization
Dimers
Gadolinium
Magnetic properties
Materials science
Molecular structure
Molecules
Separation
Asymmetric units
Carboxylates
Homologous compounds
Isostructural compounds
Organometallics
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v59_n12_pm1121_Baggio
http://hdl.handle.net/20.500.12110/paper_16005368_v59_n12_pm1121_Baggio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_16005368_v59_n12_pm1121_Baggio
record_format dspace
spelling paper:paper_16005368_v59_n12_pm1121_Baggio2023-06-08T16:24:57Z Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate Characterization Dimers Gadolinium Magnetic properties Materials science Molecular structure Molecules Separation Asymmetric units Carboxylates Homologous compounds Isostructural compounds Organometallics The title compound, [Dy2(C4H5O 2)6(C12H8N2) 2]·H2O, crystallizes as dimeric units with an inversion center. Each Dy atom is nine-coordinate, by seven O atoms from trans-2-butenoate groups and two N atoms from a phenanthroline molecule. The dimer is quadruply bridged by trans-2-butenoates (two η1: η1:μ2 and two η1:η1: μ2 bridges). The intradimer Dy⋯Dy separation is 3.9003 (5) Å. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved. 2003 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v59_n12_pm1121_Baggio http://hdl.handle.net/20.500.12110/paper_16005368_v59_n12_pm1121_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Characterization
Dimers
Gadolinium
Magnetic properties
Materials science
Molecular structure
Molecules
Separation
Asymmetric units
Carboxylates
Homologous compounds
Isostructural compounds
Organometallics
spellingShingle Characterization
Dimers
Gadolinium
Magnetic properties
Materials science
Molecular structure
Molecules
Separation
Asymmetric units
Carboxylates
Homologous compounds
Isostructural compounds
Organometallics
Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate
topic_facet Characterization
Dimers
Gadolinium
Magnetic properties
Materials science
Molecular structure
Molecules
Separation
Asymmetric units
Carboxylates
Homologous compounds
Isostructural compounds
Organometallics
description The title compound, [Dy2(C4H5O 2)6(C12H8N2) 2]·H2O, crystallizes as dimeric units with an inversion center. Each Dy atom is nine-coordinate, by seven O atoms from trans-2-butenoate groups and two N atoms from a phenanthroline molecule. The dimer is quadruply bridged by trans-2-butenoates (two η1: η1:μ2 and two η1:η1: μ2 bridges). The intradimer Dy⋯Dy separation is 3.9003 (5) Å. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.
title Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate
title_short Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate
title_full Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate
title_fullStr Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate
title_full_unstemmed Di-μ-trans-2-butenoato-κ3O,O,O′-di-μ-trans-2- butenoato-κ2O,O′-bis[(trans-2-butenoato- κ2O,O′)(1,10-phenanthroline-κ2N, N′)dysprosium(III)] dihydrate
title_sort di-μ-trans-2-butenoato-κ3o,o,o′-di-μ-trans-2- butenoato-κ2o,o′-bis[(trans-2-butenoato- κ2o,o′)(1,10-phenanthroline-κ2n, n′)dysprosium(iii)] dihydrate
publishDate 2003
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v59_n12_pm1121_Baggio
http://hdl.handle.net/20.500.12110/paper_16005368_v59_n12_pm1121_Baggio
_version_ 1768546368919437312

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