Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae

A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(μ-NC)(M)]2-/-/2+ (L = tpy, 2,2′-6′, 2′′-terpyridine, or tpm, tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine, M = RuII(CN)5, Os III(CN)5, OsII(CN)5, Ru II(py)4(CN), py = pyridine) have been synthesized and fully char...

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Detalles Bibliográficos
Autores principales: Cadranel, Alejandro, Albores, Pablo, Baraldo Victorica, Luis Mario
Publicado: 2013
Materias:
Bimetallic compound
Bipyridines
Building blockes
Cyanide-bridged
General formulas
Intra-molecular electron transfer
Photophysical properties
Terpyridines
Cyanides
Methane
Osmium
Synthesis (chemical)
Rubidium compounds
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v42_n48_p16723_Cadranel
http://hdl.handle.net/20.500.12110/paper_14779226_v42_n48_p16723_Cadranel
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_14779226_v42_n48_p16723_Cadranel
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spelling paper:paper_14779226_v42_n48_p16723_Cadranel2023-06-08T16:18:13Z Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae Cadranel, Alejandro Albores, Pablo Baraldo Victorica, Luis Mario Bimetallic compound Bipyridines Building blockes Cyanide-bridged General formulas Intra-molecular electron transfer Photophysical properties Terpyridines Cyanides Methane Osmium Synthesis (chemical) Rubidium compounds A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(μ-NC)(M)]2-/-/2+ (L = tpy, 2,2′-6′, 2′′-terpyridine, or tpm, tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine, M = RuII(CN)5, Os III(CN)5, OsII(CN)5, Ru II(py)4(CN), py = pyridine) have been synthesized and fully characterized. Most of them present MLCT emission (λ = 690-730 nm, Φ = 10-3-10-4) and their photophysical properties resemble the ones of the respective mononuclear Ru(L)(bpy) species. The exception is when M is OsIII(CN)5, where an intramolecular electron transfer quenching mechanism is proposed. The conditions that should be met for avoiding the reductive or oxidative quenching of the excited state are also discussed. © 2013 The Royal Society of Chemistry. Fil:Cadranel, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Alborés, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baraldo, L.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2013 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v42_n48_p16723_Cadranel http://hdl.handle.net/20.500.12110/paper_14779226_v42_n48_p16723_Cadranel
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Bimetallic compound
Bipyridines
Building blockes
Cyanide-bridged
General formulas
Intra-molecular electron transfer
Photophysical properties
Terpyridines
Cyanides
Methane
Osmium
Synthesis (chemical)
Rubidium compounds
spellingShingle Bimetallic compound
Bipyridines
Building blockes
Cyanide-bridged
General formulas
Intra-molecular electron transfer
Photophysical properties
Terpyridines
Cyanides
Methane
Osmium
Synthesis (chemical)
Rubidium compounds
Cadranel, Alejandro
Albores, Pablo
Baraldo Victorica, Luis Mario
Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
topic_facet Bimetallic compound
Bipyridines
Building blockes
Cyanide-bridged
General formulas
Intra-molecular electron transfer
Photophysical properties
Terpyridines
Cyanides
Methane
Osmium
Synthesis (chemical)
Rubidium compounds
description A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(μ-NC)(M)]2-/-/2+ (L = tpy, 2,2′-6′, 2′′-terpyridine, or tpm, tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine, M = RuII(CN)5, Os III(CN)5, OsII(CN)5, Ru II(py)4(CN), py = pyridine) have been synthesized and fully characterized. Most of them present MLCT emission (λ = 690-730 nm, Φ = 10-3-10-4) and their photophysical properties resemble the ones of the respective mononuclear Ru(L)(bpy) species. The exception is when M is OsIII(CN)5, where an intramolecular electron transfer quenching mechanism is proposed. The conditions that should be met for avoiding the reductive or oxidative quenching of the excited state are also discussed. © 2013 The Royal Society of Chemistry.
author Cadranel, Alejandro
Albores, Pablo
Baraldo Victorica, Luis Mario
author_facet Cadranel, Alejandro
Albores, Pablo
Baraldo Victorica, Luis Mario
author_sort Cadranel, Alejandro
title Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
title_short Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
title_full Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
title_fullStr Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
title_full_unstemmed Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
title_sort emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
publishDate 2013
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v42_n48_p16723_Cadranel
http://hdl.handle.net/20.500.12110/paper_14779226_v42_n48_p16723_Cadranel
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AT alborespablo emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae
AT baraldovictoricaluismario emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae
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