Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center

The coordination of a modified rhodamine B (Rhod) to a bis-bipyridine ruthenium (ii) (Ru-bpy) phototrigger complex enables a photodissociation reaction at longer wavelengths through enhanced absorption of green light (532 nm). The very high molar absorptivity of rhodamine (∼105 M -1 cm-1) and the hi...

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Publicado: 2012
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1474905X_v11_n5_p843_Filevich
http://hdl.handle.net/20.500.12110/paper_1474905X_v11_n5_p843_Filevich
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_1474905X_v11_n5_p843_Filevich
record_format dspace
spelling paper:paper_1474905X_v11_n5_p843_Filevich2023-06-08T16:17:38Z Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center The coordination of a modified rhodamine B (Rhod) to a bis-bipyridine ruthenium (ii) (Ru-bpy) phototrigger complex enables a photodissociation reaction at longer wavelengths through enhanced absorption of green light (532 nm). The very high molar absorptivity of rhodamine (∼105 M -1 cm-1) and the high quantum efficiency of Förster resonance energy transfer (FRET) from rhodamine to the Ru-bpy center (0.84) result in an unusually high photosensitivity and uncaging cross-section of the Ru-bpy-rhodamine complex at longer wavelengths. © The Royal Society of Chemistry and Owner Societies 2012. 2012 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1474905X_v11_n5_p843_Filevich http://hdl.handle.net/20.500.12110/paper_1474905X_v11_n5_p843_Filevich
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The coordination of a modified rhodamine B (Rhod) to a bis-bipyridine ruthenium (ii) (Ru-bpy) phototrigger complex enables a photodissociation reaction at longer wavelengths through enhanced absorption of green light (532 nm). The very high molar absorptivity of rhodamine (∼105 M -1 cm-1) and the high quantum efficiency of Förster resonance energy transfer (FRET) from rhodamine to the Ru-bpy center (0.84) result in an unusually high photosensitivity and uncaging cross-section of the Ru-bpy-rhodamine complex at longer wavelengths. © The Royal Society of Chemistry and Owner Societies 2012.
title Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
spellingShingle Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
title_short Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
title_full Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
title_fullStr Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
title_full_unstemmed Energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
title_sort energy transfer from a rhodamine antenna to a ruthenium-bipyridine center
publishDate 2012
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1474905X_v11_n5_p843_Filevich
http://hdl.handle.net/20.500.12110/paper_1474905X_v11_n5_p843_Filevich
_version_ 1768542565831802880

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