Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution

The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The result...

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Publicado: 1976
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n11_p1256_Nudelman
http://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_1472779X_v_n11_p1256_Nudelman
record_format dspace
spelling paper:paper_1472779X_v_n11_p1256_Nudelman2025-07-30T18:53:09Z Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The results prove that an experimental failure to detect a solvolysis product is not evidence for a negligible solvolysis rate. 1976 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n11_p1256_Nudelman http://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The results prove that an experimental failure to detect a solvolysis product is not evidence for a negligible solvolysis rate.
title Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
spellingShingle Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
title_short Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
title_full Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
title_fullStr Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
title_full_unstemmed Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
title_sort kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
publishDate 1976
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n11_p1256_Nudelman
http://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman
_version_ 1840324902223085568

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