Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction
The known 1,4-anhydro-2,3,6-tri-O-benzyl-D-galactopyranose (1) has been regioselectively ring-opened using a variety of nucleophiles under acidic conditions to exclusively afford furanosides.
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2000
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1434193X_v_n21_p3523_Kovensky http://hdl.handle.net/20.500.12110/paper_1434193X_v_n21_p3523_Kovensky |
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paper:paper_1434193X_v_n21_p3523_Kovensky2023-06-08T16:14:24Z Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction Kovensky, José Eduardo Anhydro sugars Carbohydrates Enzymes Galactofuranosides Glycosides 1,4 anhydro 2,3,6 tri o benzyl beta galactopyranose galactofuranoside derivative pyranoside unclassified drug article catalysis chemical reaction kinetics chemical structure isotope labeling nuclear magnetic resonance spectroscopy reaction analysis structure analysis synthesis The known 1,4-anhydro-2,3,6-tri-O-benzyl-D-galactopyranose (1) has been regioselectively ring-opened using a variety of nucleophiles under acidic conditions to exclusively afford furanosides. Fil:Kovensky, J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2000 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1434193X_v_n21_p3523_Kovensky http://hdl.handle.net/20.500.12110/paper_1434193X_v_n21_p3523_Kovensky |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Anhydro sugars Carbohydrates Enzymes Galactofuranosides Glycosides 1,4 anhydro 2,3,6 tri o benzyl beta galactopyranose galactofuranoside derivative pyranoside unclassified drug article catalysis chemical reaction kinetics chemical structure isotope labeling nuclear magnetic resonance spectroscopy reaction analysis structure analysis synthesis |
| spellingShingle |
Anhydro sugars Carbohydrates Enzymes Galactofuranosides Glycosides 1,4 anhydro 2,3,6 tri o benzyl beta galactopyranose galactofuranoside derivative pyranoside unclassified drug article catalysis chemical reaction kinetics chemical structure isotope labeling nuclear magnetic resonance spectroscopy reaction analysis structure analysis synthesis Kovensky, José Eduardo Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction |
| topic_facet |
Anhydro sugars Carbohydrates Enzymes Galactofuranosides Glycosides 1,4 anhydro 2,3,6 tri o benzyl beta galactopyranose galactofuranoside derivative pyranoside unclassified drug article catalysis chemical reaction kinetics chemical structure isotope labeling nuclear magnetic resonance spectroscopy reaction analysis structure analysis synthesis |
| description |
The known 1,4-anhydro-2,3,6-tri-O-benzyl-D-galactopyranose (1) has been regioselectively ring-opened using a variety of nucleophiles under acidic conditions to exclusively afford furanosides. |
| author |
Kovensky, José Eduardo |
| author_facet |
Kovensky, José Eduardo |
| author_sort |
Kovensky, José Eduardo |
| title |
Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction |
| title_short |
Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction |
| title_full |
Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction |
| title_fullStr |
Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction |
| title_full_unstemmed |
Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction |
| title_sort |
synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: a possible chemical model for an unprecedented enzymatic reaction |
| publishDate |
2000 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1434193X_v_n21_p3523_Kovensky http://hdl.handle.net/20.500.12110/paper_1434193X_v_n21_p3523_Kovensky |
| work_keys_str_mv |
AT kovenskyjoseeduardo synthesisofgalactofuranosidesbyregioselectiveringopeningofa14anhydrogalactopyranosederivativeapossiblechemicalmodelforanunprecedentedenzymaticreaction |
| _version_ |
1768542611088343040 |