A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in whic...
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2009
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v48_n49_p9366_Albores http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores |
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paper:paper_14337851_v48_n49_p9366_Albores |
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paper:paper_14337851_v48_n49_p9366_Albores2025-07-30T18:50:06Z A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,. 2009 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v48_n49_p9366_Albores http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds |
| spellingShingle |
Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| topic_facet |
Cluster compounds Cobalt Dicarboxypyrazine Magnetic properties Chemical equations Cluster compounds Dinuclear Mixed-valent compounds Spin ground state Chemical reactions Cobalt Magnetic properties Cobalt compounds |
| description |
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,. |
| title |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| title_short |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| title_full |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| title_fullStr |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| title_full_unstemmed |
A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| title_sort |
co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine |
| publishDate |
2009 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v48_n49_p9366_Albores http://hdl.handle.net/20.500.12110/paper_14337851_v48_n49_p9366_Albores |
| _version_ |
1840323422036426752 |