Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure

Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalys...

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Publicado: 2001
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14203049_v6_n12_p1006_Romanelli
http://hdl.handle.net/20.500.12110/paper_14203049_v6_n12_p1006_Romanelli
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spelling paper:paper_14203049_v6_n12_p1006_Romanelli2023-06-08T16:13:46Z Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure Heteropolyacids Methoxymethyl ethers Phenols Protecting groups Well-Dawson catalyst acid ester derivative organic solvent phenol derivative silicon dioxide catalysis catalyst chemical reaction kinetics chemical structure conference paper deprotection reaction quantitative analysis reaction time temperature dependence Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable. 2001 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14203049_v6_n12_p1006_Romanelli http://hdl.handle.net/20.500.12110/paper_14203049_v6_n12_p1006_Romanelli
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Heteropolyacids
Methoxymethyl ethers
Phenols
Protecting groups
Well-Dawson catalyst
acid
ester derivative
organic solvent
phenol derivative
silicon dioxide
catalysis
catalyst
chemical reaction kinetics
chemical structure
conference paper
deprotection reaction
quantitative analysis
reaction time
temperature dependence
spellingShingle Heteropolyacids
Methoxymethyl ethers
Phenols
Protecting groups
Well-Dawson catalyst
acid
ester derivative
organic solvent
phenol derivative
silicon dioxide
catalysis
catalyst
chemical reaction kinetics
chemical structure
conference paper
deprotection reaction
quantitative analysis
reaction time
temperature dependence
Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
topic_facet Heteropolyacids
Methoxymethyl ethers
Phenols
Protecting groups
Well-Dawson catalyst
acid
ester derivative
organic solvent
phenol derivative
silicon dioxide
catalysis
catalyst
chemical reaction kinetics
chemical structure
conference paper
deprotection reaction
quantitative analysis
reaction time
temperature dependence
description Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable.
title Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_short Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_full Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_fullStr Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_full_unstemmed Efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with Wells-Dawson structure
title_sort efficient deprotection of phenol methoxymethyl ethers using a solid acid catalyst with wells-dawson structure
publishDate 2001
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14203049_v6_n12_p1006_Romanelli
http://hdl.handle.net/20.500.12110/paper_14203049_v6_n12_p1006_Romanelli
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