Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes
The electrocatalytic hydrogenation of ethyl pyruvate to yield S-ethyl lactate over palladium supported on carbon felt electrodes modified with cinchonidine has been found to yield an enantiomeric excess of 13%. The effect of electrode potential, ethyl pyruvate concentration and cinchonidine have bee...
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2007
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v9_n11_p2725_Vago http://hdl.handle.net/20.500.12110/paper_13882481_v9_n11_p2725_Vago |
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paper:paper_13882481_v9_n11_p2725_Vago2023-06-08T16:13:05Z Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters The electrocatalytic hydrogenation of ethyl pyruvate to yield S-ethyl lactate over palladium supported on carbon felt electrodes modified with cinchonidine has been found to yield an enantiomeric excess of 13%. The effect of electrode potential, ethyl pyruvate concentration and cinchonidine have been investigated. The experimental results reported in the present study are in good agreement with the previously reported heterogeneous enantioselective hydrogenation using molecular hydrogen at high pressure. The electrocatalytic driven reaction avoids the dissociation of molecular hydrogen and thus the use of high pressure hydrogen. © 2007 Elsevier B.V. All rights reserved. 2007 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v9_n11_p2725_Vago http://hdl.handle.net/20.500.12110/paper_13882481_v9_n11_p2725_Vago |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters |
| spellingShingle |
Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| topic_facet |
Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters |
| description |
The electrocatalytic hydrogenation of ethyl pyruvate to yield S-ethyl lactate over palladium supported on carbon felt electrodes modified with cinchonidine has been found to yield an enantiomeric excess of 13%. The effect of electrode potential, ethyl pyruvate concentration and cinchonidine have been investigated. The experimental results reported in the present study are in good agreement with the previously reported heterogeneous enantioselective hydrogenation using molecular hydrogen at high pressure. The electrocatalytic driven reaction avoids the dissociation of molecular hydrogen and thus the use of high pressure hydrogen. © 2007 Elsevier B.V. All rights reserved. |
| title |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_short |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_full |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_fullStr |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_full_unstemmed |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_sort |
enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported pd electrodes |
| publishDate |
2007 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v9_n11_p2725_Vago http://hdl.handle.net/20.500.12110/paper_13882481_v9_n11_p2725_Vago |
| _version_ |
1768546082716909568 |