Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel

Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10...

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Autores principales: Völker, Edgar, Calvo, Ernesto Julio
Publicado: 2006
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v8_n1_p179_Volker
http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker
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spelling paper:paper_13882481_v8_n1_p179_Volker2023-06-08T16:13:05Z Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel Völker, Edgar Calvo, Ernesto Julio Localised corrosion Scanning electrochemical microscopy SECM Tin-free steel Tinplate Carbon steel Corrosion Electrochemistry Epoxy resins Oxidation Precipitation (chemical) Scanning electron microscopy Localized corrosion SECM Tin-free steel Tinplate Ions Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10 mM H2SO4 in order to avoid Fe(OH)3 precipitation. The SECM was employed in the collection mode at constant height (≈ 10-15 μm) on an x-y plane above the sample, monitoring the tip current as a function of tip location. © 2005 Elsevier B.V. All rights reserved. Fil:Völker, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v8_n1_p179_Volker http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Localised corrosion
Scanning electrochemical microscopy
SECM
Tin-free steel
Tinplate
Carbon steel
Corrosion
Electrochemistry
Epoxy resins
Oxidation
Precipitation (chemical)
Scanning electron microscopy
Localized corrosion
SECM
Tin-free steel
Tinplate
Ions
spellingShingle Localised corrosion
Scanning electrochemical microscopy
SECM
Tin-free steel
Tinplate
Carbon steel
Corrosion
Electrochemistry
Epoxy resins
Oxidation
Precipitation (chemical)
Scanning electron microscopy
Localized corrosion
SECM
Tin-free steel
Tinplate
Ions
Völker, Edgar
Calvo, Ernesto Julio
Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
topic_facet Localised corrosion
Scanning electrochemical microscopy
SECM
Tin-free steel
Tinplate
Carbon steel
Corrosion
Electrochemistry
Epoxy resins
Oxidation
Precipitation (chemical)
Scanning electron microscopy
Localized corrosion
SECM
Tin-free steel
Tinplate
Ions
description Local fluxes of ferrous ions at low carbon steel surfaces coated with tin and an epoxy-phenolic resin on tinplate samples, and at chrome steel (tin-free steel) have been monitored by oxidation of Fe2+ ions at the tip of a Pt scanning electrochemical microscope (SECM). The samples were immersed in 10 mM H2SO4 in order to avoid Fe(OH)3 precipitation. The SECM was employed in the collection mode at constant height (≈ 10-15 μm) on an x-y plane above the sample, monitoring the tip current as a function of tip location. © 2005 Elsevier B.V. All rights reserved.
author Völker, Edgar
Calvo, Ernesto Julio
author_facet Völker, Edgar
Calvo, Ernesto Julio
author_sort Völker, Edgar
title Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_short Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_full Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_fullStr Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_full_unstemmed Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
title_sort scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel
publishDate 2006
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v8_n1_p179_Volker
http://hdl.handle.net/20.500.12110/paper_13882481_v8_n1_p179_Volker
work_keys_str_mv AT volkeredgar scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel
AT calvoernestojulio scanningelectrochemicalmicroscopymeasurementofferrousionfluxesduringlocalizedcorrosionofsteel
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