Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution
DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution...
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paper:paper_13882481_v80_n_p16_Mozhzhukhina2023-06-08T16:13:04Z Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution Mendez De Leo, Lucila Paula Williams, Federico Jose Calvo, Ernesto Julio Air Battery CO2 DMSO Lithium Oxygen Air Carbon Carbon dioxide Dimethyl sulfoxide Electric batteries Electrolytes Electrolytic reduction Lithium Organic solvents Oxygen Battery Carbon dioxide evolution DMSO Li-air batteries Oxygen evolution reaction Oxygen reduction reaction Research communities Solvent decompositions Lithium batteries DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on Au in dimethyl sulfoxide-based electrolyte for Li-air battery by a combination of in-situ analytical tools: EQCM, SNIFTIRS, DEMS and XPS, in particular the evolution of CO2 from the solvent decomposition. © 2017 Elsevier B.V. Fil:Mendez De Leo, L.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Williams, F.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2017 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v80_n_p16_Mozhzhukhina http://hdl.handle.net/20.500.12110/paper_13882481_v80_n_p16_Mozhzhukhina |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Air Battery CO2 DMSO Lithium Oxygen Air Carbon Carbon dioxide Dimethyl sulfoxide Electric batteries Electrolytes Electrolytic reduction Lithium Organic solvents Oxygen Battery Carbon dioxide evolution DMSO Li-air batteries Oxygen evolution reaction Oxygen reduction reaction Research communities Solvent decompositions Lithium batteries |
| spellingShingle |
Air Battery CO2 DMSO Lithium Oxygen Air Carbon Carbon dioxide Dimethyl sulfoxide Electric batteries Electrolytes Electrolytic reduction Lithium Organic solvents Oxygen Battery Carbon dioxide evolution DMSO Li-air batteries Oxygen evolution reaction Oxygen reduction reaction Research communities Solvent decompositions Lithium batteries Mendez De Leo, Lucila Paula Williams, Federico Jose Calvo, Ernesto Julio Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
| topic_facet |
Air Battery CO2 DMSO Lithium Oxygen Air Carbon Carbon dioxide Dimethyl sulfoxide Electric batteries Electrolytes Electrolytic reduction Lithium Organic solvents Oxygen Battery Carbon dioxide evolution DMSO Li-air batteries Oxygen evolution reaction Oxygen reduction reaction Research communities Solvent decompositions Lithium batteries |
| description |
DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on Au in dimethyl sulfoxide-based electrolyte for Li-air battery by a combination of in-situ analytical tools: EQCM, SNIFTIRS, DEMS and XPS, in particular the evolution of CO2 from the solvent decomposition. © 2017 Elsevier B.V. |
| author |
Mendez De Leo, Lucila Paula Williams, Federico Jose Calvo, Ernesto Julio |
| author_facet |
Mendez De Leo, Lucila Paula Williams, Federico Jose Calvo, Ernesto Julio |
| author_sort |
Mendez De Leo, Lucila Paula |
| title |
Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
| title_short |
Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
| title_full |
Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
| title_fullStr |
Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
| title_full_unstemmed |
Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
| title_sort |
insights into dimethyl sulfoxide decomposition in li-o2 battery: understanding carbon dioxide evolution |
| publishDate |
2017 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v80_n_p16_Mozhzhukhina http://hdl.handle.net/20.500.12110/paper_13882481_v80_n_p16_Mozhzhukhina |
| work_keys_str_mv |
AT mendezdeleolucilapaula insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution AT williamsfedericojose insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution AT calvoernestojulio insightsintodimethylsulfoxidedecompositioninlio2batteryunderstandingcarbondioxideevolution |
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1768541953015676928 |