Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response

Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the po...

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Autores principales: Cortez, María Lorena, Cukierman, Ana Lea, Battaglini, Fernando
Publicado: 2009
Materias:
Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Self-assembling
Anionic surfactants
Diffusers (optical)
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v11_n5_p990_Cortez
http://hdl.handle.net/20.500.12110/paper_13882481_v11_n5_p990_Cortez
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_13882481_v11_n5_p990_Cortez
record_format dspace
spelling paper:paper_13882481_v11_n5_p990_Cortez2023-06-08T16:13:02Z Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response Cortez, María Lorena Cukierman, Ana Lea Battaglini, Fernando Electrocatalysis Glucose oxidase Materials Osmium polypyridil complex Poly(allylamine) Redox-active polyelectrolyte Sodium dodecyl sulfate Catalytic behaviors Catalytic response Enzyme systems Hydrophobic interactions Multi-layer systems Poly(allylamine) Redox-active polyelectrolyte Self-assembling Sodium dodecyl sulfate Anionic surfactants Diffusers (optical) Electrocatalysis Enzymes Glucose Glucose sensors Hydrophobicity Multilayers Osmium Polyelectrolytes Polymers Sodium Sodium sulfate Surface treatment Glucose oxidase Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the polyelectrolyte and the enzyme uptake at pH 7.0, enhancing its catalytic behavior in presence of glucose more than 5 times, compared to the system (PAOs/GOx)n constructed at the same pH. The balance between ionic and hydrophobic interactions in the construction of this system is discussed. © 2009 Elsevier B.V. All rights reserved. Fil:Cortez, M.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukierman, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Battaglini, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2009 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v11_n5_p990_Cortez http://hdl.handle.net/20.500.12110/paper_13882481_v11_n5_p990_Cortez
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Poly(allylamine)
Redox-active polyelectrolyte
Self-assembling
Sodium dodecyl sulfate
Anionic surfactants
Diffusers (optical)
Electrocatalysis
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Glucose oxidase
spellingShingle Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Poly(allylamine)
Redox-active polyelectrolyte
Self-assembling
Sodium dodecyl sulfate
Anionic surfactants
Diffusers (optical)
Electrocatalysis
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Glucose oxidase
Cortez, María Lorena
Cukierman, Ana Lea
Battaglini, Fernando
Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
topic_facet Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Poly(allylamine)
Redox-active polyelectrolyte
Self-assembling
Sodium dodecyl sulfate
Anionic surfactants
Diffusers (optical)
Electrocatalysis
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Glucose oxidase
description Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the polyelectrolyte and the enzyme uptake at pH 7.0, enhancing its catalytic behavior in presence of glucose more than 5 times, compared to the system (PAOs/GOx)n constructed at the same pH. The balance between ionic and hydrophobic interactions in the construction of this system is discussed. © 2009 Elsevier B.V. All rights reserved.
author Cortez, María Lorena
Cukierman, Ana Lea
Battaglini, Fernando
author_facet Cortez, María Lorena
Cukierman, Ana Lea
Battaglini, Fernando
author_sort Cortez, María Lorena
title Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_short Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_full Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_fullStr Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_full_unstemmed Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_sort surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
publishDate 2009
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v11_n5_p990_Cortez
http://hdl.handle.net/20.500.12110/paper_13882481_v11_n5_p990_Cortez
work_keys_str_mv AT cortezmarialorena surfactantpresenceinamultilayerpolyelectrolyteenzymesystemimprovesitscatalyticresponse
AT cukiermananalea surfactantpresenceinamultilayerpolyelectrolyteenzymesystemimprovesitscatalyticresponse
AT battaglinifernando surfactantpresenceinamultilayerpolyelectrolyteenzymesystemimprovesitscatalyticresponse
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