Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route

Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition o...

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Autor principal: Oestreicher, Victor Santiago Jesus
Publicado: 2017
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher
http://hdl.handle.net/20.500.12110/paper_13597345_v53_n24_p3466_Oestreicher
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spelling paper:paper_13597345_v53_n24_p3466_Oestreicher2023-06-08T16:11:31Z Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route Oestreicher, Victor Santiago Jesus copper chloride epoxide nitrogen propylene oxide adsorption alkalinization aqueous solution Article crystallization desorption one pot synthesis precipitation Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates. © The Royal Society of Chemistry. Fil:Oestreicher, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2017 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher http://hdl.handle.net/20.500.12110/paper_13597345_v53_n24_p3466_Oestreicher
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic copper chloride
epoxide
nitrogen
propylene oxide
adsorption
alkalinization
aqueous solution
Article
crystallization
desorption
one pot synthesis
precipitation
spellingShingle copper chloride
epoxide
nitrogen
propylene oxide
adsorption
alkalinization
aqueous solution
Article
crystallization
desorption
one pot synthesis
precipitation
Oestreicher, Victor Santiago Jesus
Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
topic_facet copper chloride
epoxide
nitrogen
propylene oxide
adsorption
alkalinization
aqueous solution
Article
crystallization
desorption
one pot synthesis
precipitation
description Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates. © The Royal Society of Chemistry.
author Oestreicher, Victor Santiago Jesus
author_facet Oestreicher, Victor Santiago Jesus
author_sort Oestreicher, Victor Santiago Jesus
title Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_short Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_full Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_fullStr Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_full_unstemmed Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_sort extremely efficient crystallization of hkust-1 and keggin-loaded related phases through the epoxide route
publishDate 2017
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher
http://hdl.handle.net/20.500.12110/paper_13597345_v53_n24_p3466_Oestreicher
work_keys_str_mv AT oestreichervictorsantiagojesus extremelyefficientcrystallizationofhkust1andkegginloadedrelatedphasesthroughtheepoxideroute
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