Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition o...
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paper:paper_13597345_v53_n24_p3466_Oestreicher2023-06-08T16:11:31Z Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route Oestreicher, Victor Santiago Jesus copper chloride epoxide nitrogen propylene oxide adsorption alkalinization aqueous solution Article crystallization desorption one pot synthesis precipitation Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates. © The Royal Society of Chemistry. Fil:Oestreicher, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2017 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher http://hdl.handle.net/20.500.12110/paper_13597345_v53_n24_p3466_Oestreicher |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
copper chloride epoxide nitrogen propylene oxide adsorption alkalinization aqueous solution Article crystallization desorption one pot synthesis precipitation |
spellingShingle |
copper chloride epoxide nitrogen propylene oxide adsorption alkalinization aqueous solution Article crystallization desorption one pot synthesis precipitation Oestreicher, Victor Santiago Jesus Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route |
topic_facet |
copper chloride epoxide nitrogen propylene oxide adsorption alkalinization aqueous solution Article crystallization desorption one pot synthesis precipitation |
description |
Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates. © The Royal Society of Chemistry. |
author |
Oestreicher, Victor Santiago Jesus |
author_facet |
Oestreicher, Victor Santiago Jesus |
author_sort |
Oestreicher, Victor Santiago Jesus |
title |
Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route |
title_short |
Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route |
title_full |
Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route |
title_fullStr |
Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route |
title_full_unstemmed |
Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route |
title_sort |
extremely efficient crystallization of hkust-1 and keggin-loaded related phases through the epoxide route |
publishDate |
2017 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v53_n24_p3466_Oestreicher http://hdl.handle.net/20.500.12110/paper_13597345_v53_n24_p3466_Oestreicher |
work_keys_str_mv |
AT oestreichervictorsantiagojesus extremelyefficientcrystallizationofhkust1andkegginloadedrelatedphasesthroughtheepoxideroute |
_version_ |
1768541811220938752 |