A kinetic study of ethanol steam reforming using a nickel based catalyst
A kinetic study of ethanol steam reforming to produce hydrogen within the region of kinetic rate control was carried out. A Ni(II)-Al(III) lamellar double hydroxide as catalyst precursor was used. H2, CO, CO2 and CH4 were obtained as products. Using the Langmuir-Hinshelwood (L-H) approach, two kinet...
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2008
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10225528_v51_n1-4_p39_Mas http://hdl.handle.net/20.500.12110/paper_10225528_v51_n1-4_p39_Mas |
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paper:paper_10225528_v51_n1-4_p39_Mas2023-06-08T16:00:07Z A kinetic study of ethanol steam reforming using a nickel based catalyst Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming A kinetic study of ethanol steam reforming to produce hydrogen within the region of kinetic rate control was carried out. A Ni(II)-Al(III) lamellar double hydroxide as catalyst precursor was used. H2, CO, CO2 and CH4 were obtained as products. Using the Langmuir-Hinshelwood (L-H) approach, two kinetic models were proposed. The first was a general model including four reactions, two of them corresponding to ethanol steam reforming and the other two to methane steam reforming. When high temperatures and/or high water/ethanol feed ratios were used, the system could be reduced to two irreversible ethanol steam reforming reactions. © Springer Science+Business Media, LLC 2008. 2008 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10225528_v51_n1-4_p39_Mas http://hdl.handle.net/20.500.12110/paper_10225528_v51_n1-4_p39_Mas |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming |
| spellingShingle |
Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming A kinetic study of ethanol steam reforming using a nickel based catalyst |
| topic_facet |
Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming |
| description |
A kinetic study of ethanol steam reforming to produce hydrogen within the region of kinetic rate control was carried out. A Ni(II)-Al(III) lamellar double hydroxide as catalyst precursor was used. H2, CO, CO2 and CH4 were obtained as products. Using the Langmuir-Hinshelwood (L-H) approach, two kinetic models were proposed. The first was a general model including four reactions, two of them corresponding to ethanol steam reforming and the other two to methane steam reforming. When high temperatures and/or high water/ethanol feed ratios were used, the system could be reduced to two irreversible ethanol steam reforming reactions. © Springer Science+Business Media, LLC 2008. |
| title |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_short |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_full |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_fullStr |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_full_unstemmed |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_sort |
kinetic study of ethanol steam reforming using a nickel based catalyst |
| publishDate |
2008 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10225528_v51_n1-4_p39_Mas http://hdl.handle.net/20.500.12110/paper_10225528_v51_n1-4_p39_Mas |
| _version_ |
1768545060352163840 |