Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine
The synthesis of tetrakis(1,1-dimethyl-2-trimethylammonium)ethylphthalocyaninato Zn(II) tetraiodide 2 - a new cationic phthalocyanine - is reported as well as its photophysical properties in water, relevant for the use of this dye as photodynamic sensitizer. The hydrophobicity of the macrocycle lead...
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1997
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10111344_v41_n3_p227_Fernandez http://hdl.handle.net/20.500.12110/paper_10111344_v41_n3_p227_Fernandez |
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paper:paper_10111344_v41_n3_p227_Fernandez2023-06-08T15:59:40Z Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine Cationic phthalocyanine Phthalocyanine Zinc dye photosensitizing agent phthalocyanine zinc singlet oxygen absorption spectroscopy aqueous solution article dimerization drug synthesis hydrophobicity light absorption photochemistry photodynamic therapy priority journal Cations Dimerization Fluorescence Fluorescent Dyes Indoles Molecular Structure Organometallic Compounds Oxygen Radiation-Sensitizing Agents Singlet Oxygen Solubility Water Zinc The synthesis of tetrakis(1,1-dimethyl-2-trimethylammonium)ethylphthalocyaninato Zn(II) tetraiodide 2 - a new cationic phthalocyanine - is reported as well as its photophysical properties in water, relevant for the use of this dye as photodynamic sensitizer. The hydrophobicity of the macrocycle leads to strong aggregation which lowers the fluorescence and singlet oxygen quantum yields of aqueous solutions of 2. Photophysical parameters agree with those of other Zn phthalocyanines when correction is performed for the fraction of light absorbed by the monomer. 1997 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10111344_v41_n3_p227_Fernandez http://hdl.handle.net/20.500.12110/paper_10111344_v41_n3_p227_Fernandez |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Cationic phthalocyanine Phthalocyanine Zinc dye photosensitizing agent phthalocyanine zinc singlet oxygen absorption spectroscopy aqueous solution article dimerization drug synthesis hydrophobicity light absorption photochemistry photodynamic therapy priority journal Cations Dimerization Fluorescence Fluorescent Dyes Indoles Molecular Structure Organometallic Compounds Oxygen Radiation-Sensitizing Agents Singlet Oxygen Solubility Water Zinc |
| spellingShingle |
Cationic phthalocyanine Phthalocyanine Zinc dye photosensitizing agent phthalocyanine zinc singlet oxygen absorption spectroscopy aqueous solution article dimerization drug synthesis hydrophobicity light absorption photochemistry photodynamic therapy priority journal Cations Dimerization Fluorescence Fluorescent Dyes Indoles Molecular Structure Organometallic Compounds Oxygen Radiation-Sensitizing Agents Singlet Oxygen Solubility Water Zinc Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine |
| topic_facet |
Cationic phthalocyanine Phthalocyanine Zinc dye photosensitizing agent phthalocyanine zinc singlet oxygen absorption spectroscopy aqueous solution article dimerization drug synthesis hydrophobicity light absorption photochemistry photodynamic therapy priority journal Cations Dimerization Fluorescence Fluorescent Dyes Indoles Molecular Structure Organometallic Compounds Oxygen Radiation-Sensitizing Agents Singlet Oxygen Solubility Water Zinc |
| description |
The synthesis of tetrakis(1,1-dimethyl-2-trimethylammonium)ethylphthalocyaninato Zn(II) tetraiodide 2 - a new cationic phthalocyanine - is reported as well as its photophysical properties in water, relevant for the use of this dye as photodynamic sensitizer. The hydrophobicity of the macrocycle leads to strong aggregation which lowers the fluorescence and singlet oxygen quantum yields of aqueous solutions of 2. Photophysical parameters agree with those of other Zn phthalocyanines when correction is performed for the fraction of light absorbed by the monomer. |
| title |
Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine |
| title_short |
Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine |
| title_full |
Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine |
| title_fullStr |
Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine |
| title_full_unstemmed |
Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine |
| title_sort |
synthesis and photophysical properties of a new cationic water-soluble zn phthalocyanine |
| publishDate |
1997 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10111344_v41_n3_p227_Fernandez http://hdl.handle.net/20.500.12110/paper_10111344_v41_n3_p227_Fernandez |
| _version_ |
1768545199681699840 |