Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds

Highly ordered hybrid metallic-polymeric assemblies were prepared by simultaneously combining two organization-directing tools: the liquid crystalline behavior of high aspect ratio silver nanowires (Ag-NWs) dispersed in poly(vinyl alcohol) (PVA) aqueous solutions and a cryogenic technique based on t...

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Publicado: 2012
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09599428_v22_n18_p9195_Romeo
http://hdl.handle.net/20.500.12110/paper_09599428_v22_n18_p9195_Romeo
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spelling paper:paper_09599428_v22_n18_p9195_Romeo2023-06-08T15:57:16Z Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds Aqueous dispersions Cryogenic techniques Electrically conductive High aspect ratio Liquid crystalline system Macroporous Poly(vinyl alcohol) (PVA) Silver nanowires Aspect ratio Freezing Hybrid materials Liquid crystals Polymers Silver Highly ordered hybrid metallic-polymeric assemblies were prepared by simultaneously combining two organization-directing tools: the liquid crystalline behavior of high aspect ratio silver nanowires (Ag-NWs) dispersed in poly(vinyl alcohol) (PVA) aqueous solutions and a cryogenic technique based on the directional freezing of the liquid crystal-like systems. This combination allowed us to render highly oriented Ag-NWs inside macroporous PVA scaffolds. As a consequence of the compact self-assembly of NWs into the structured composites, electrically conductive metallic-polymeric hybrid materials were obtained. © 2012 The Royal Society of Chemistry. 2012 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09599428_v22_n18_p9195_Romeo http://hdl.handle.net/20.500.12110/paper_09599428_v22_n18_p9195_Romeo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Aqueous dispersions
Cryogenic techniques
Electrically conductive
High aspect ratio
Liquid crystalline system
Macroporous
Poly(vinyl alcohol) (PVA)
Silver nanowires
Aspect ratio
Freezing
Hybrid materials
Liquid crystals
Polymers
Silver
spellingShingle Aqueous dispersions
Cryogenic techniques
Electrically conductive
High aspect ratio
Liquid crystalline system
Macroporous
Poly(vinyl alcohol) (PVA)
Silver nanowires
Aspect ratio
Freezing
Hybrid materials
Liquid crystals
Polymers
Silver
Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
topic_facet Aqueous dispersions
Cryogenic techniques
Electrically conductive
High aspect ratio
Liquid crystalline system
Macroporous
Poly(vinyl alcohol) (PVA)
Silver nanowires
Aspect ratio
Freezing
Hybrid materials
Liquid crystals
Polymers
Silver
description Highly ordered hybrid metallic-polymeric assemblies were prepared by simultaneously combining two organization-directing tools: the liquid crystalline behavior of high aspect ratio silver nanowires (Ag-NWs) dispersed in poly(vinyl alcohol) (PVA) aqueous solutions and a cryogenic technique based on the directional freezing of the liquid crystal-like systems. This combination allowed us to render highly oriented Ag-NWs inside macroporous PVA scaffolds. As a consequence of the compact self-assembly of NWs into the structured composites, electrically conductive metallic-polymeric hybrid materials were obtained. © 2012 The Royal Society of Chemistry.
title Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
title_short Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
title_full Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
title_fullStr Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
title_full_unstemmed Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
title_sort directional freezing of liquid crystalline systems: from silver nanowire/pva aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
publishDate 2012
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09599428_v22_n18_p9195_Romeo
http://hdl.handle.net/20.500.12110/paper_09599428_v22_n18_p9195_Romeo
_version_ 1768544922667843584