The aromatic carbon-carbon ipso-substitution reaction

The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in aryl...

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Publicado:	2010
Materias:	Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09476539_v16_n46_p13572_Bonesi http://hdl.handle.net/20.500.12110/paper_09476539_v16_n46_p13572_Bonesi
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_09476539_v16_n46_p13572_Bonesi
record_format	dspace
spelling	paper:paper_09476539_v16_n46_p13572_Bonesi2023-06-08T15:53:56Z The aromatic carbon-carbon ipso-substitution reaction Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in arylation reactions will be illustrated accordingly for the preparation of biphenyl-, vinyl-, alkynyl-, and alkyl-substituted aromatics. Getting the bond back together: The strategies are unveiled for an aromatic C-C ipso-substitution reaction. This process allows for the one-pot cleavage of Ar-C bonds (e.g., in alkyl and acyl (hetero)aromatics, in benzonitriles, in α,α- disubstituted arylmethanols, and in carboxylic acids) for the formation of a new Ar-C bond (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 2010 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09476539_v16_n46_p13572_Bonesi http://hdl.handle.net/20.500.12110/paper_09476539_v16_n46_p13572_Bonesi
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds
spellingShingle	Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds The aromatic carbon-carbon ipso-substitution reaction
topic_facet	Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds
description	The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in arylation reactions will be illustrated accordingly for the preparation of biphenyl-, vinyl-, alkynyl-, and alkyl-substituted aromatics. Getting the bond back together: The strategies are unveiled for an aromatic C-C ipso-substitution reaction. This process allows for the one-pot cleavage of Ar-C bonds (e.g., in alkyl and acyl (hetero)aromatics, in benzonitriles, in α,α- disubstituted arylmethanols, and in carboxylic acids) for the formation of a new Ar-C bond (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
title	The aromatic carbon-carbon ipso-substitution reaction
title_short	The aromatic carbon-carbon ipso-substitution reaction
title_full	The aromatic carbon-carbon ipso-substitution reaction
title_fullStr	The aromatic carbon-carbon ipso-substitution reaction
title_full_unstemmed	The aromatic carbon-carbon ipso-substitution reaction
title_sort	aromatic carbon-carbon ipso-substitution reaction
publishDate	2010
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09476539_v16_n46_p13572_Bonesi http://hdl.handle.net/20.500.12110/paper_09476539_v16_n46_p13572_Bonesi
_version_	1768541712155672576

The aromatic carbon-carbon ipso-substitution reaction

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